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简介：Theadsorptiveremovalofarsenicbysynthetically-preparednanoFe-Mnbinaryoxides（FM）wasinvestigated.AnovelmethodusingpotassiumpermanganateandferricchlorideasrawmaterialswasusedtosynthesiseFM.ThemolarratioofFeandMninthesyntheticFe-Mnbinaryoxideswas4:3.TheFM-1andFM-2（preparedatdifferentactivationtemperatures）havinghighspecificsurfaceareas（358.87and128.58m2/g,respectively）wereamorphousandofnanoparticletypes.TheamountofarsenicadsorbedonFM-1washigherthanthatadsorbedonFM-2particles.AfteradsorptionbyFM-1,residualarsenicconcentrationdecreasedtolessthan10μg/L.Theadsorptionkineticsdatawereanalyzedusingdifferentkineticmodelsincludingpseudofirst-ordermodel,pseudosecond-ordermodel,Elovichmodelandintraparticlediffusionmodel.Pseudosecond-orderkineticmodelwasthemostappropriatemodeltodescribetheadsorptionkinetics.TheadsorptionpercentageofAs（Ⅲ）increasedinthepHrangeof2–3whileitdecreasedwiththeincreaseofpH（3

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简介：Thevolcano-sedimentarysuccessionaroundWadiZaghrainSinai,atthenorthernmostsegmentoftheArabianNubianShield,comprisesvolcanicrocksinterbeddedwithratherimmaturesediments.Thesuccessionisdominatedbyintermediatetosilicicvolcanicsofmedium-tohigh-Kcalc-alkalineaffinity.Itisdividedintotwounits,thelowerunitincludesintermediaterocksanddacitesinterbeddedwithgraywackes,semi-pelitesandpelitesandtoppedbypolymictconglomerates.Thisunitissubjectedtofoldingandregionalmetamorphism(uptogarnetzone)andisintrudedbyquartzdiorite-granodioriteinducing,locally,low-pressurecontactthermalmetamorphism.Theunmetamorphosedupperunitencompassesacidvolcanicsintercalatedwithlitharenite,sublithareniteandminorarenite.Therhyolitesofthisunitpertaintothehighlyfractionatedgranitesandarecharacterizedbyanagpaiticindex(NK/A)rangingfrom0.87to0.96.Theymayreflecteitherextensiveinteractionofsubduction-relatedmagmaswiththecontinentalcrustorachangeinthetectonicregime.Thepresentlithologicalandgeochemicalcharacteristicsofthestudiedsedimentstogetherwithavailablezirconagesindicateratherdistalprovenanceoftheirdetritus.Thisdetrituscomprisesfluvial-alluvialsedimentsaccumulatedintheintermontanebasins,whicharehalf-grabensortiltedfaultblocks.Thetectonicsettingofthedepositionalbasinsisactivecontinentalmarginandcontinentalislandarcs.GeochemicalpatternsoftheZaghravolcano-sedimentarysuccessionindicatetheircorrelationwiththeDokhanVolcanics-HammamatClasticssequenceoftheEasternDesertofEgypt.Also,theZaghravolcanicsdisplaygeochemicalsimilaritieswiththoseexposedinSinai,attheRutig,FeraniandIqnaShar’aareas.TheZaghrasuccessionisdatedasEdiacaranbutisnotrelatedeithertotheensimaticislandarcassemblageortotherift-relatedassemblageformedduringtheearlystagesofthebreak-upofRodiniaaspreviouslythought.

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简介：WeperformedasystematictraceandrareearthelementanalysisforthebeddedFe-MncarbonaterocksrelatedtothestratiformAg-Pb-ZnmineralizationintheLengshuikengoredistrict,JiangxiProvince,SouthChina.ThreetypesofFe-Mncarbonatesaredistinguished,namely,themassive,breccia,andveintypes.Bothcarbonateandsilicatefractionsinthesamplesareanalyzedfortheirtraceandrareearthelementconcentrationsusingastepacid-leachingtechnique.OurresultsshowthatthecarbonatefractionsinthemassivetypesampleshavethelowestREEconcentrationsbutpronouncedpositiveEuandYanomalieswithEu/Eu*valuefrom1.3to6.2andY/Hovaluefrom40.1to59.5,andsimilarcharacteristicsarealsoshownforthesilicatefractionsinthemassivetypesamples(Eu/Eu*=1.0–6.7,Y/Ho=20.7–55.1).TheseREEcharacteristicsaresimilartothoseofSedextypemassivesulfidedepositsworldwide,andwesuggestthatthemassivetypeFe-Mncarbonaterockswerelikelyformedfromanexhalativevolcanic-hydrothermalfluidfeedingthedepressionbasinofavolcaniclake.Thehighconcentrationsofredox-sensitiveelementsandratiossuchasU/Th,V/CrandV/(V+Ni)indicateadysoxicenvironmentfortheFe-Mncarbonatedeposition.Incontrast,thebrecciatypeandveintypeFe-Mncarbonatesamplesshowdifferenttraceandrareearthelementfeaturesfromthoseofmassivetypesamples,andtheyaremoresimilartothevolcanicrocksandmagmatic-hydrothermalfluidsintheLengshuikengoredistrictandmayreflectstrongoverprintingfromvolcanicandsub-volcanicmagmatismrelatedtotheporphyrytypemineralizationinthedistrict.