简介:AsustainablestrategyforFischer–Tropschironcatalystsissuccessfullyachievedbyembeddingofsynergisticpromotersfromarenewableresource,corncob.Theiron-basedcatalysts,namedas“corncob-driven”catalysts,arecomposedofironspeciessupportedoncarbonasprimaryactivecomponentsandvariousminerals(K,Mg,Ca,andSi,etc.)aspromoters.Thecorncob-drivencatalystsarefacilelysynthesizedbyaone-pothydrothermaltreatmentundermildconditions.Thecharacterizationresultsindicatethattheformationofironcarbidesfromhumboldtineisclearlyenhancedandthemorphologyofcatalystparticlestendstobemoreregularmicrospheresafteraddingcorncob.Itisobservedthattheoptimizedcorncob-drivencatalystexhibitsahigherconversionthanwithoutpromoters’catalystinFischer–Tropschsynthesis(ca.73%vs.ca.49%).Moreimportantly,asynergisticeffectexistsinmultiplepromotersfromcorncobthatcanenhanceheavyhydrocarbonsselectivityandlowerCO2selectivity,obviouslydifferentfromthecatalystwithpromotersfromchemicals.Theproposedsynthesisrouteofcorncob-drivencatalystsprovidesnewstrategiesfortheutilizationofrenewableresourcesandeliminationofenvironmentalpollutantsfromchemicalpromoters.
简介:Carbonnanotube(CNT)-supportedRunanoparticleswithmeansizesrangingfrom2.3to9.2nmwerepreparedbydifferentpost-treatmentsandstudiedforFischer-Tropsch(FT)synthesis.TheeffectsofRuparticlesizeoncatalyticbehaviorswereinvestigatedatbothshorterandlongercontacttimes.Atshortercontacttime,wherethesecondaryreactionswereinsignificant,theturnoverfrequency(TOF)forCOconversionwasdependentonthemeansizeofRuparticles;TOFincreasedwiththemeansizeofRuparticlesfrom2.3to6.3nmandthendecreasedslightly.Atthesametime,theselectivitiestoC5+hydrocarbonsincreasedgraduallywiththemeansizeofRuparticlesupto6.3nmandthenkeptalmostunchangedwithafurtherincreaseinRuparticlesize.Atlongercontacttime,C10-C20selectivityincreasedsignificantlyattheexpenseofC21+selectivity,suggestingtheoccurrenceoftheselectivehydrocrackingofC21+toC10-C20hydrocarbons.
简介:摘要目的对Fischer编制的简版就医态度量表(attitudes toward medical help-seeking scale,ATMHSS)进行汉化,并分析就医态度量表中文版在中国居民群体中的信度和效度。方法以方便取样的方法,选取来自不同城市居民769名,进行问卷调查,通过项目分析及探索性因素分析初步筛选,确定量表最终项目。检验ATMHSS的中文修订版的信度和效度。结果通过探索性因子分析,共提取四个主因子,分别为行为意向(10个条目)、非宿命论(10个条目)、医疗信任(6个条目)和非回避态度(4个条目)。ATMHSS各维度与总分相关系数在0.641~0.839之间,各维度相关系数在0.213~0.556之间。ATMHSS与各效标变量均呈显著正相关(r=0.406~0.696,均P<0.01)。验证性因素分析结果显示,各项目拟合度良好(χ2=752.572,df=391,χ2/df=1.925,RMSEA=0.045,SRMR=0.058,CFI=0.902,GFI=0.903,IFI=0.903,TLI=0.891)。ATMHSS的内部一致性信度在0.726~0.879之间,重测信度在0.622~0.736之间。结论ATMHSS中文修订版信效度良好,可作为测量就医态度的有力工具。
简介:Thl-responseplaysacrucialroleindeterminingpathogenesisoforgan-specificautoimmunediseases.ItisbelievedthatbothIL-12andINF-αareinitiatorstoregulateTh1-response.Inourexperimentalautoimmuneuveitis(EAU)model,bothLewisandFischer344ratssharethesameMHCclassⅡImolecules,whileLewisratisEAUsusceptibleandFischer344ratisEAUresistant.However,underthesameconditionofimmunization,ifpertussistoxin(PTX)wasinjectedintraperitoneallyasanadditionaladjuvant,Fischer344ratcandevelopEAU.InthisstudyweinvestigatewhichmechanismsareinvolvedintheinductionofEAUinCFA+R16+PTX-treated(CRP-treated)Fischer344rats.InvivoandinvitrodatademonstratedthatThl-cytokine,IFN-γmRNAexpressionwassignificantlyincreasedindiseasetargettissue-eyesandindraininglymphnodecellsofCRP-treatedFischer344rat.WhenIL-12andIFN-αmRNAexpressionwerecomparedintheexperimentalgroups,onlyIFN-αmRNAexpressionwasassociatedwithEAUdevelopment.TodistinguishthesourcesofIFN-αproducingcells,itwasobservedthatIFN-αexpressionwasmainlyproducedbymacrophages.ItwasfurtherconfirmedthatnormalmacrophagefromFischer344ratwasabletoproducesignificantIFN-αinthepresenceofPTX.ThedatastronglysuggestedthatIFN-αmightbeinvolvedininitiatingThl-celldifferentiationandinturncontributetotheinductionofEAU.HighIFN-αexpressioninducedbyPTXmayrepresentanovelpathwaytoinitiateThlresponseinFischer344rat.
简介:ThedetailedkineticsofFischer-TropschsynthesisoveranindustrialFe/Cu/La/Sicatalystwasstudiedinacontinuousspinningbasketreactorundertheconditionsrelevanttoindustrialoperations.ReactionrateequationswerederivedonthebasisofLangmuir-HinshelwoodHougen-WatsontypemodelsforFischer-Tropschsynthesisbasedonpossiblereactionssetsoriginatedfromthecarbide,enolicandcombinedenol/carbidemechanisms.Kineticmodelcandidateswereevaluatedbytheglobaloptimizationofkineticparameters,whichwererealizedbyfirstminimizationofmulti-responseobjectivefunctionswithconventionalLevenberg-Marquardtmethod.Itwasfoundthatanenolicmechanismbasedmodelcouldproduceagoodfitoftheexperimentaldata.Theactivationenergyforparaffinformationis95kJmol-1whichissmallerthanthatforolefinformation(121kJmol-1).
简介:K-promotediron/carbonnanotubescomposite(i.e.,FeK-OX)waspreparedbyaredoxreactionbetweencarbonnanotubesandK_2FeO_4followedbythermaltreatmentsonapurposeastheFischer–Tropschcatalystforthedirectconversionofsyngastolowerolefins.ItscatalyticbehaviorswerecomparedwiththoseoftheothertwoFe-IMandFeK-IMcatalystspreparedbyimpregnationmethodfollowedbythermaltreatments.ThenovelFeK-OXcompositecatalystisfoundtoexhibithigherhydrocarbonselectivity,lowerolefinsselectivityandchaingrowthprobabilityaswellasbetterstability.ThecatalyststructureperformancerelationshiphasbeenestablishedusingmultipletechniquesincludingXRD,Raman,TEMandEDSelementalmapping.Inaddition,effectsofadditionalpotassiumintotheFeK-OXcompositecatalystontheFTOperformancewerealsoinvestigatedanddiscussed.Additionalpotassiumpromotersfurtherendowthecatalystswithhigheryieldoflowerolefins.Theseresultsdemonstratedthattheintroductionmethodofpromotersandironspeciesplaysacrucialroleinthedesignandfabricationofhighlyactive,selectiveandstableiron-basedcompositecatalystsfortheFTOreaction.
简介:Aseriesof3wt%Ruembeddedonorderedmesoporouscarbon(OMC)catalystswithdifferentporesizeswerepreparedbyautoreductionbetweenrutheniumprecursorsandcarbonsourcesat1123K.RunanoparticleswereembeddedonthecarbonwallsofOMC.CharacterizationtechnologiesincludingpowerX-raydiffraction(XRD),nitrogenadsorption-desorption,transmissionelectronmicroscopy(TEM),andhydrogentemperature-programmedreduction(H2-TPR)wereusedtoscrutinizethecatalysts.ThecatalystactivityforFischer-Tropschsynthesis(FTS)wasmeasuredinafixedbedreactor.Itwasrevealedthat3wt%Ru-OMCcatalystsexhibitedhighlyorderedmesoporousstructureandlargesurfacearea.Comparedwiththecatalystswithsmallerpores,thecatalystswithlargerporeswereinclinedtoformlargerRuparticles.These3wt%Ru-OMCcatalystswithdifferentporesizesweremorestablethan3wt%Ru/ACcatalystduringtheFTSreactionsbecauseRuparticleswereembeddedonthecarbonwalls,suppressingparticlesaggregation,movementandoxidation.ThecatalyticactivityandC5+selectivitywerefoundtoincreasewiththeincreasingporesize,however,CH4selectivityshowedtheoppositetrend.ThesechangesmaybeexplainedintermsofthespecialenvironmentoftheactiveRusitesandthediffusionofproductsintheporesofthecatalysts,suggestingthattheactivityandhydrocarbonselectivityaremoredependentontheporesizeofOMCthanontheRuparticlesize.
简介:[摘要]以函数思想来贯穿中学数学内容更有利于提高数学教学质量,在培养学生的创新精神和应用数学知识解决问题的过程中,函数思想具有其他思想方法所不及的指导作用。因此,数学教学应大力加强对函数思想的进一步研究,并努力将函数思想渗透到一切可能的教学内容中去。[关键词]初中数学教学数学思想函数思想知识结构教学质量九年义务教育阶段的数学课程,致力于使学生获得适应未来社会生活和进一步发展所必需的重要数学事实以及基本的数学思想方法和必要的应用技能。把数学思想作为基础知识进行传授是加强素质教育的一项创举。我们认为,以函数思想来贯穿中学数学内容更有利于提高数学教学质量。在培养学生的创新精神和应用数学知识解决问题的过程中,函数思想具有其他思想方法所不及的指导作用。因此,在教学中把函数思想渗透到一切可能的教学内容中去......