简介:Thetetranuclearalkyltin(Ⅳ)compounds{[R2Sn(C9H8N3O3)O]SnR3}2[R=n-Bu(1),4-CNC6H4CH2(2),C6H5CH2(3),4-ClC6H4CH2(4)]werepreparedbythereactionofSchiffbaseligandpyruvicacidisonicotinylhydrazonewith(R3Sn)2Ointhecorrespondingmolarratioof1:1.Allcompoundshavebeencharacterizedbyelementalanalysis,IRand^1HNMRspectra.Thecrystalstructureofcompound1wasdeterminedbyX-raysinglecrystaldiffractionalanalysis.Thiscompoundexhibitsadimericstructurecontainingdistannoxaneunitswithtwotypesofthetinatoms.Forthefirsttinatom,itappearstobeseven-coordinatedwithadistortedpentagonalbipyramidgeometry,andtheotherisfive-coordinatedwithadistortedtrigonalbipyramidalgeometry.Themoleculesarepackedintheunitcellintwo-dimensionalnetworkstructurethroughaninteractionbetweentheNatomsofthepyridineandthetinatomsofanadjacentmolecule.
简介:Thesolidaddofthefirstprotonatedzincoborophosphate,(H3O)Zn(H2O)2BP2O8·H2O(1),wassoventothermallysyn-thesizedbythereactionofZn(NO3)2·6H2OandH3BO3withH3PO4inamixedsolvent,andstructurallycharacterizedbysingle-ystalX-raydiffractionanalysis.ItcrystallizesinthehexagonalP6122,a=0.9604(4)nm,c=1.5297(6)nm,V=1.2218(8)nm^3,Dc=2.921g/cm^3,Z=6,F(000)=1080,μ=3.495mm^-1.Thestmchwefeaturesthatthetetrahedra-te-trahedrahdlcesinterconnectedbyoctahedraandstronghydro-gembondinteractionsformathree-dimensionalframework.Theprotonatedwatermoleculesarelocatedatuniquepositions.othercharacterizationsbyIRandthermalanalysisarealsode-scribed.
简介:ThecomplexK3H4GeW9V3O40·8H2OcrystallizedinamonocliiniesystemwithspacegroupP2,Mr=2784.67,a=11.099(3),b=16.452(4),c=13.534(4),β=108.14°,Z=2,V=2348.493,F(000):2456,μ=239.7cm-1,De=3.932g/cm3.ThefinalR=0.083for4528non-zeroreflexions.ThestructureofanionsGeW9V3O40andGeW9O34belongstoA--type.
简介:<正>1.所谓“O(的)V(的)N”指这种偏正短语:a.语言运用角度b.语言运用的角度c.语言的运用角度d.语言的运用的角度我们用“O”代表动词语“V”(“运用”)前的V”的受事成分(“语言”),“N”代表“V”后那个名词语(“角度”),括号里的“的”表示有时出现,有时不出现。本文想要探讨的是如何分析“O(的)V(的)N”的内部层次关系。层次关系不同,该短语所属的类型自然也就不同。例拿a来说,下面的切分表示这是一个带有多层定语的偏正短语:a1语言运用角度而下面的切分则表示这是一个由偏正短语充当定语的偏正短语:a2语言运用角度
简介:AnO'-Sialon-Al2O3compositerefractorywaspreparedbyinsitureactionofSi3N4-ZrSiO4-Al2O3mixturewithfusedaluminaaggregates.Densification,insitureactionprocedureandmicrostructureofthematerialwereinvestigatedbymeansofX-raydiffraction,opticalandscanningelectronicmicroscopesandEDAX.
简介:采用数值计算方法对氧化亚氮/丙烷(N2O/C3H8)发动机样机气液同轴离心式喷嘴的喷雾性能进行了研究,得到了环缝外喷嘴气相喷注压降和内喷嘴缩进深度对离心式喷嘴喷雾流场的影响.分析结果表明,较低的气相喷注压降(<0.3MPa)会显著的影响液滴在流场中的蒸发速率以及流场流强、混合比、索太尔平均直径(SMD)和n值的分布;气相喷注压降从0.3MPa增加至0.6MPa,稳定喷雾流场液滴SMD和n值分别在2.41~1.68,2.03~0.98范围内变化并逐渐减小.内喷嘴缩进深度从0mm增加至6mm,稳定喷雾流场液滴的SMD和n值受其影响较小,均分别在1.70~0.94,2.36~0.99范围内波动.喷嘴的最佳燃烧区主要分布在下游轴向位置0.015~0.035m范围内并随着气相喷注压降的升高和内喷嘴缩进深度的增大逐渐靠近喷嘴出口.该设计喷嘴在发动机热试实验中表现出很好的性能.
简介:ThecrystalstructureofN-(2,3,4,6-tetra-O-acetyl-β-D-gly-cosyl)-thiocarbamicbenzoylhydrazine(C22H27N3O9S)wasdeterminedbyX-raydiffractonmethod.Thehexopyranosylringadoptsachairconformation.Alltheringsubstituentsareintheequatorialpositions.Theacetoxyl-methylgroupisinsynclinalconformation.TheSatomisinsynperiplanarconformationwhilethebenzoylhydrazinemoietyisanti-periplanar.Thethiocarbamicmoietyisalmostcompanarwiththebenzoylhydrazinegroup.Therearetwointramolecularhydrogenbondsandoneintermolecularhydrogenbondforeachmoleculeinthecrystalstructure.Themoleculesformanetworkstructurethroughintermolecularhydrogenbonds.
简介:用柠檬酸溶胶-凝胶工艺制备出了LiV3O8化合物,并检测了其作为热电池阴极材料时的放电性能,干凝胶210℃焙烧所得的粉末颗粒疏松多孔,300℃时可变成结晶岩状,低温焙烧时出现了Li0.3V2O5和LiV2O5相,经650℃长时间保温后可转变为LiV3O8,模拟Li-B/LiCl-KCl/LiV3O8(或V2O5)热电池500℃放电试验表明,LiV3O8因具有良好的电子导电体和较低的Li+扩散极化,其放电较V2O5平稳,虽峰值电压略有降低,但可利用的比容量(电压降至峰值电压的75%或2.0V)均不低于V2O5;LiV3O8中掺入8%的P2O5时可提高小电流放电时的电压。