简介：A60%Fe/Al2O3catalystwaspreparedbytheco-precipitationmethod.ItwasreducedbyH2toproducemetallicFe,whichwasthensulfidedbyCS2toFe0.96SandFe3S4orphosphidedbytriphenylphosphine(PPh3)inliquidphasestoFe2PandFeP.Itwasfoundthattheironsulfides(Fe0.96SandFe3S4)exhibitedthelowactivityforthehydrodesulfurization(HDS)reactions.TheHDSactivitywasalsolowontheFe(metal)/Al2O3andFe2P/Al2O3catalystssincetheywereconvertedintoFe0.96SandFe3S4duringtheHDSreactions.Incontrast,theFeP/Al2O3wasfoundtobestableandactivefortheHDSreactions.Inparticular,FeP/Al2O3possessedsignificantlysmallerFePparticlesthanFeP/C,leadingtothesignificanthigherHDSactivityofFeP/Al2O3thanFeP/C.

简介：摘要目前光伏电站建设大规模发展，其中电缆的用量庞大，电缆的截面对工程的经济运行影响较大。因此必须重视光伏发电系统设计中对电缆经济截面的选择。本文总结了光伏发电系统直流电缆的选型原则，并提出采用差额净现值法来计算直流电缆的经济截面积的方法。

简介：用微波高温固相法合成了Er^3+单掺Lu2O3,Li^+与Er^3+共掺Lu2O3及Li^+,Zn^2+,Mg^2+掺杂Lu2O3∶Er^3+的荧光粉。实验表明金属离子Li^+、Zn^2+、Mg^2+、Er^3+掺杂Lu2O3,不影响Lu2O3的立方晶相。扫描电子显微镜测量表明,Li^+掺杂可以有效改善粉体的分散性和形貌,Li^+,Zn^2+,Mg^2+共掺杂获得的粉体颗粒分布更加均匀,粒径范围为80~100nm。379nm激发下,Li^+与Er^3+共掺样品发光较单掺Er^3+样品在565nm处的发光增强了4.5倍,而Li^+、Zn^2+、Mg^2+与Er^3+共掺样品较其发光增强5.3倍。980nm激发下,Li^+与Er^3+共掺样品,Li^+、Zn^2+、Mg^2+与Er^3+共掺样品的发光分别比单掺Er^3+样品在565nm处发光增强23倍与39倍,在662nm处发光强度分别增强20倍与43倍。379nm激发下,较单掺Er3+的样品,掺杂Li^+的样品和Li^+,Zn^2+,Mg^2+和Er^3+共掺的样品荧光寿命均有所增加,而Zn^2+、Er^3+共掺及Mg^2+、Er^3+共掺样品的荧光寿命则有所缩短。

简介：Thesuppressionoftherecombinationofelectronsandholes(e–h)andtheenhancementofthelightabsorptionofsemiconductorsaretwokeypointstowardefficientphotocatalyticdegradation.Here,wereportafew-layerg-C3N4/α-MoO3nanoneedles(flg-C3N4/α-MoO3NNs)all-solid-stateZ-schememechanismphotocatalystsynthesizedviaatypicalhydrothermalmethodinacontrolledmanner.Therecombinationofthephoto-inducede–hpairscouldbeeffectivelyrestrainedbytheZ-schemepassagewaybetweentheflg-C3N4andα-MoO3NNsinthecomposite,whichcouldalsopromiseahighredoxabilitytodegradepollutants.Anditbecamepossibleforthepreparedphotocatalysttoabsorblightinawiderangeofwavelengths.Thedetailedmechanismwasstudiedbyelectronspin-resonancespectroscopy(ESR).Thelow-dimensionalnanostructureofthetwoconstituents(α-MoO3NNswithone-dimensionalstructureandflg-C3N4withtwo-dimensionalstructure)endowedthecompositewithvarietiesofexcellentphysicochemicalproperties,whichfacilitatedthetransferanddiffusionofthephotoelectronsandincreasedthespecificsurfaceareaandtheactivesites.The10wt%flg-C3N4/α-MoO3NNsshowedthebestphotocatalyticperformancetowardRhBdegradation,therateofwhichwas71.86%,~2.6timeshigherthanthatofα-MoO3NNs.

简介：利用2-羟甲基吡啶(Hhmp)、三乙胺和Mn(CH3COO)2在室温下反应,合成了2D分子基磁性配位聚合物[Mn3Ⅱ(CH3COO)6(H2O)4·(H2O)2]n,其结晶为单斜空间群P21/c.在标题化合物中,Mn2+通过乙酸根离子连接形成线性三核Mn3(CH3COO)6单元;这些单元进一步通过乙酸根离子连接形成1个具有4-连接节点的二维层状44拓扑结构;最后,层与层之间通过氢键连接形成3D超分子网络结构.磁性研究表明,由于缺少反转中心,标题化合物在低温时表现出自旋倾斜反铁磁有序,这在纯乙酸基团构筑的体系中比较少见.

简介：Atemperature-inducedspinreorientationtransitionbetweenГ4(Gx,Ay,Fz)andГ2(Fx,Cy,Gz)hasbeenstudiedinthefamilyofEr1–xYxFeO3(x=0,0.25,0.5,0.75,1)singlecrystals.BydopingnonmagneticY3+,wetunedthespinreorientationtemperaturetolowtemperaturewithincreasingx.Moreover,thetypicalcompensationpointandspinfliptransitionofErFeO3alsodecreaseswithdoping,anddisappearsabovex=0.75.WealsoreporttheRietveldrefinementsandRamanspectroscopyofEr1–xYxFeO3,wheresomeRamanpeaksareshiftedtolowfrequencywithincreasingdoping.Ourresultsshedlightontheunderstandingoftheinteractionbetweentwomagneticsub-latticesofrareearth(R3+)andiron(Fe3+)ions,andwillalsocontributetothematerialsdesignandpotentialapplications.

简介：摘要现阶段，3D打印技术的快速发展和进步，引起了全球范围内的普遍关注。3D打印技术成熟性迅速提升，其打印速度及准确性也随之持续提升，同时所需打印成本有所减少。所以说，相当一部分人觉得3D打印技术必然会引发“第三次工业革命”。

简介：

简介：Nanosheet(S)andnanoplate(P)γ-Al2O3weresynthesizedbysimplehydrothermalmethodsandemployedassupportsforNicatalystsinCO2methanation.BothofthenanostructuredNi/Al2O3catalystsdisplayedgoodactivity.Incomparison,theNi/Al2O3-ScatalystshowedhigherCO2conversionthantheNi/Al2O3-Pcounterpartatthereactiontemperaturerangingfrom250to400°C.ThephysicalandchemicalpropertiesofthecatalystsweresystematicallycharacterizedbyN2sorption,X-raydiffraction(XRD),highresolution-transmissionelectronmicroscopy(HR-TEM),hydrogentemperature-programmedreduction(H2-TPR)andCO2temperature-programmeddesorption(CO2-TPD)techniques.Higherspecificsurfaceareaandstrongermetal-supportinteractionswereconfirmedontheNi/Al2O3-Scatalyst,whichmayleadtosmallerparticlesizeofNinanoparticles.Moreover,theNi/Al2O3-Scatalystpossessedmoreabundantweakandmediumbasicsites,whichwouldbenefittheactivationofCO2.ThesmallerNisizeandmoresuitablebasicsitesmayrationalizethesuperioractivityoftheNi/Al2O3-Scatalyst.Besides,theNi/Al2O3-Scatalystexhibitedexcellentstabilityat325°Cfor40h.

简介：Recently,bismuthsulfide(Bi2S3)hasattractedmuchattentioninthethermoelectriccommunityowingtoitsabundance,lowcost,andadvancedproperties.However,itspoorelectricaltransportpropertieshavepreventedBi2S3devicesfromrealizinghighthermoelectricperformance.Inthiswork,ourmotivationistodecreasethelargeelectricalresistivity,whichisrecognizedastheoriginofthelowZTvalueinundopedBi2S3.Wecombinedmeltingandsparkplasmasintering(SPS)inacontinuousfabricationprocesstoproduceBi2S3–xSex(x=0,0.09,0.15,0.21)andBi2S2.85–ySe0.15Cly(y=0.0015,0.0045,0.0075,0.015,0.03)samples.OurresultsshowthatSealloyingatSsitescannarrowthebandgapandactivateintrinsicelectronconduction,leadingtoahighpowerfactorof~2.0μW·cm–1·K–2atroomtemperatureinBi2S2.85S0.15,about100timeshigherthanthatofundopedBi2S3.Moreover,ourfurtherintroductionofClatomsintotheSsitesresultedinasecond-stageoptimizationofcarrierconcentrationandsimultaneouslyreducedthelatticethermalconductivity,whichcontributedtoahighZTvalueof~0.6at723KforBi2S2.835Se0.15Cl0.015.OurresultsindicatethathighthermoelectricperformancecouldberealizedinBi2S3withearth-abundantandlow-costelements.

简介：Synthesis,structureandmagneticpropertiesofRudopedperovskitestructuredmanganiteLa0.5Sr0.5MnO3wereinvestigatedexperimentally.Ahydrothermalmethodwasusedforthepreparationofthesamples.Ahigh-temperatureannealingprocesswasalsoemployedtomakeacomparison.AslightlyenhancementoftheunitcellvolumewasobservedwiththeincreaseofRuconcentration.Scanningelectronmicroscopyshowsthatthematerialsaremadeupofcube-shapedparticleswithdimensionofseveralmicrometers.Importantly,itisfoundthatboththeCurietemperatureTCandsaturationmomentcanbereducedbyRudoping.ThevalueofcoercivefieldisnotaffectedbytheintroductionofRu.

简介：AfacilehydrothermalmethodwasdevelopedforthepreparationofFe2O3@CnanocompositesusingFeCl3·6H2Oasironsourceandglucoseascarbonsourceunderalkalinecondition.Themorphologyandstructureoftheas-preparedproductwereidentifiedbytransmissionelectronmicroscopy(TEM),highresolutiontransmissionelectronmicroscopy(HRTEM),field-emissionscanningelectronmicroscopy(FESEM),X-raydiffraction(XRD),Ramanspectroscopy,FourierTransforminfraredspectroscopy(FTIR),andthermogravimetricanalysis(TGA).Theas-prepareα-Fe2O3@Cnanocompositeswereemployedforsupercapacitorelectrodematerial.Thesynergisticcombinationofcarbonelectricaldouble-layercapacitanceandα-Fe2O3pseudo-capacitanceestablishedsuchnanocompositesasversatileplatformforhighperformancesupercapacitors.Thesynthesismethoddevelopedhereisexpectedtoobtainothermetaloxide/carboncomposite.

简介：为了深入研究可行的中高轨成像技术,本文从探测能力角度(用最低发射激光功率表示)深入分析和比较3种主动干涉合成孔径成像技术——傅立叶望远镜(又称为相干场成像或条纹场扫描成像)、成像相关术(又称为强度相关成像)和剪切光束成像。本文利用光电倍增管的信噪比模型和激光作用距离方程,较为细致地分析每种技术在满足单次信噪比(SNR=5)条件下的极限探测能力。通过仿真分析得出:傅立叶望远镜、成像相关术和剪切光束成像所需的最低单光束单脉冲能量分别为11.4J、0.73MJ和3.1MJ。最终得出傅立叶望远镜是上述3种主动成像技术中在目前技术水平下最适合中高轨目标(约36000km)高分辨成像的可用技术的结论。

简介：Afacilegreenlow-costcontrollablehydrothermal-thermalconversion(HTC)processfortheuniformhighaspectratioCaSiO3nanowireshasbeendevelopedusingabundantCaCl2·2H2OandNa2SiO3·9H2Oasrawmaterialswithoutanyorganicadditive.Thenanowiresexhibitedatransparentcharacteristicfromtheultraviolettovisibleregion,andtheCaSiO3:1.2%Tb3+nanophosphorswithwellpreserved1DmorphologydemonstratedstronggreenluminescencewithCIEcoordinatesof(x=0.3144,y=0.5912).Thepresentworkdefinitelyrevealsthenanowiresasapromisingstructureandfunctionintegratedhostcandidateforgreen-emittingluminescentmaterialsinlightdisplaysystemsandoptoelectronicdevices.

简介：Inthispaper,carbonmicrospherepreparedbyhydrothermaltreatmentwasactivatedbyKHCO3athightemperature,andemployedasthecatalystforVO2+/VO2+redoxreactionforvanadiumredoxflowbattery(VRFB).CarbonmicrospherecanbeetchedbyKHCO3duetothereactionbetweenthepyrolysisproductsofKHCO3andcarbonatoms.Moreover,KHCO3activationcanbringmanyoxygenfunctionalgroupsoncarbonmicrosphere,furtherimprovingthewettabilityofcatalystandincreasingtheactivesites.Theelectrocatalyticpropertiesofcarbonmicrospherefromhydrothermaltreatmentareimprovedbyhightemperaturecarbonization,andcanfurtherbeenhancedbyKHCO3activation.Amongcarbonmicrospheresamples,theVO2+/VO2+redoxreactionexhibitsthehighestelectrochemicalkineticsonKHCO3activatedsample.ThecellusingKHCO3activatedcarbonmicrosphereasthepositivecatalystdemonstrateshigherenergyefficiencyandlargerdischargecapacity,especiallyathighcurrentdensity.TheresultsrevealthatKHCO3activatedcarbonmicrosphereisanefficient,low-costcarbon-basedcatalystforVO2+/VO2+redoxreactionforVRFBsystem.

简介：Tuningthecoloroutputofrare-earthiondopedluminescentnanomaterialshasimportantscientificsignificanceforfurtherextendingapplicationsincolordisplays,lasersources,optoelectronicdevices,andbiolabeling.Inpreviousstudies,pre-designedphasemodulationofthefemtosecondlaserfieldhasbeenproventobeeffectiveintuningtheluminescenceofdopedrare-earthions.Owingtothecomplexlight–matterinteractionintheactualexperiment,thedynamicrangeandoptimalefficiencyforcolortuningcannotbedeterminedwiththepre-designedphasemodulation.Thisarticlesharesthedevelopmentofanadaptivefemtosecondpulseshapingmethodbasedonageneticalgorithm,anditsusetomanipulatethegreenandredluminescencetuninginanEr3+-dopedglassceramicunder800-nmfemtosecondlaserfieldexcitationforthefirsttime.ExperimentalresultsshowthattheintensityratioofthegreenandredUCluminescenceofthedopedEr3+ionscanbeeitherincreasedordecreasedconvenientlybythephase-shapedfemtosecondlaserfieldwithanoptimalfeedbackcontrol.Thephysicalcontrolmechanismsforthecolortuningarealsoexplainedindetail.Thisarticledemonstratesthepotentialapplicationsoftheadaptivefemtosecondpulseshapingtechniqueincontrollingthecoloroutputofdopedrare-earthions.

简介：WehavecomprehensivelyinvestigatedthefrustratedJ1-J2-J3Heisenbergmodelonasimplecubiclattice.Thismodelallowsthreeregimesofmagneticorder,viz.,(π;π;π),(0;π;π)and(0;0;π),denotedasAF1,AF2,andAF3,respectively.Theeffectsoftheinterplayofneighboringcouplingsonthemodelarestudiedintheentiretemperaturerange.Thezerotemperaturemagneticpropertiesofthismodelarediscussedutilizingthelinearspinwave(LSW)theory,nonlinearspinwave(NLSW)theory,andGreen’sfunction(GF)method.ThezerotemperaturephasediagramsevaluatedbytheLSWandNLSWmethodsareillustrated,andareobservedtoexhibitdifferentparameterboundaries.Incertainregionsandalongtheparameterboundaries,thepossiblephasetransformationsdrivenbytheparametersarediscussed.TheresultsobtainedusingtheLSW,NLSW,andGFmethodsarecomparedwiththoseobtainedusingtheseriesexpansion(SE)method,andareobservedtobeingoodagreementwhenthevalueofJ2isnotclosetotheparameterboundaries.ThegroundstateenergiesobtainedusingtheLSWandNLSWmethodsareclosetothatobtainedusingtheSEmethod.Atfinitetemperatures,onlytheGFmethodisemployedtoevaluatethemagneticproperties,andthecalculatedphasediagramisobservedtobeidenticaltotheclassicalphasediagram.Theresultsindicatethatattheparameterboundaries,atemperature-drivenfirst-orderphasetransitionbetweenAF1andAF2mayoccuralongtheboundaryline.AlongtheAF1-AF3andAF2-AF3boundarylines,AF3islessstablethanAF1andAF2.OurcalculatedcriticaltemperatureagreeswiththatobtainedusingMonteCarlosimulationsandpseudofermionfunctionalrenormalizationgroupscheme.

简介：Ultrafastfiberlasersareingreatdemandforvariousapplications,suchasopticalcommunication,spectroscopy,biomedicaldiagnosis,andindustrialfabrication.Here,wereportthehighlystablefemtosecondpulsegenerationfromaMXenemode-lockedfiberlaser.Wehavepreparedthehigh-qualityTi3C2Txnanosheetsviatheetchingmethod,andcharacterizedtheirultrafastdynamicsandbroadbandnonlinearopticalresponses.Theobviousintensity-andwavelength-dependentnonlinearresponseshavebeenobservedandinvestigated.Inaddition,ahighlystablefemtosecondfiberlaserwithsignal-to-noiseratioupto70.7dBandcentralwavelengthof1567.3nmhasbeendelivered.Thestudymayprovidesomevaluabledesignguidelinesforthedevelopmentofultrafast,broadbandnonlinearopticalmodulators,andopennewavenuestowardadvancedphotonicdevicesbasedonMXenes.

简介：采用D001阳离子交换树脂对UO3样品中的阴、阳离子进行分离,用亚沸水平衡色谱柱并进行溶液淋洗,建立了电感耦合等离子体发射光谱(ICP-OES)法测定UO3样品中硫元素的分析方法。在选定的实验条件下测定硫元素的检出限为0.24μg/mL,加标回收率在91.5%~98.5%,相对标准偏差分别为3.1%和3.2%。方法简便、快捷,准确度高,适用于UO3中硫元素含量的测定。

简介：Uptothisdate,researchersarestillfacingdifficultiestoexpandthetechnologyofdirectmethanolfuelcells(DMFCs)becauseofthehighoverpotentialrequiredtooxidizethemethanolanditsrelativelypoorperformanceduetoCOpoisoningoftheleading-highcostanodecatalyst.Inlinewiththis,wehavesuccessfullymodifiedthemorphologicalstructureandcompositionoflowcostcobaltbased-metaloxides,MCo2O4(M=ZnandNi),withthesimpleandnobleuseofpolyvinylpyrrolidone(PVP)asgrowthmodifierandsurfacestabilizerduringthesynthesisofnanoparticlesinourpreviousreports,whichshownhighelectrocatalyticactivityandstrongstability.DuetothegoodperformanceofourPVPmodifiedMCo2O4towardspseudocapacitorandoxygenevolutionreactionapplications,wedecidedtoextendourresearchstudytomethanoloxidationreaction.Remarkably,PVPmodifiedNiCo2O4electrodedirectlygrownonnickelfoamsubstrateviaasimplehydrothermalprocessexhibitedbetterperformancecomparedwithPVPmodifiedZnCo2O4andNiCo2O4withoutPVP.Ithadobtainedaremarkablylowonsetpotentialof0.285Vandhighcurrentdensityof280mAcm-2,andshowngreatstabilityandhighpoisontoleranceduringacontinuousCVcyclingandChronoamperometrytest,whichattainedhighefficiencyof86.86%and98.52%,respectively.ThesepositiveresultsofPVPmodifiedNiCo2O4electrodetowardsMORmightbeattributedtoitshierarchical3Dnanostructureswithhighlymesoporoussurfaceandlargesurfaceareawhichmayhaveprovidednumerouselectroactivesites,andtheexceptionalcorrosionstabilityofNiCo2O4electrodeinalkalinesolution.