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38 个结果
  • 简介:Rotation in Reaction 19F+51VRotationinReaction19F+51V¥WangQi;LuJun;XuHushan;LiSonglin;ZhuYongtaiandZhangYuhuIndLssi...

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  • 简介:Theeffectofbismuth(Bi)forbothVO2+/VO2+andV3+/V2+redoxcouplesinvanadiumflowbatteries(VFBs)hasbeeninvestigatedbydirectlyintroducingBionthesurfaceofcarbonfelt(CF).TheresultsshowthatBihasnocatalyticeffectforVO2+/VO2+redoxcouple.Duringthefirstchargeprocess,BiisoxidizedtoBi3+(neverreturnbacktoBimetalinthesubsequentcycles)duetothelowstandardredoxpotentialof0.308V(vs.SHE)forBi3+/BiredoxcouplecomparedwithVO2+/VO2+redoxcoupleandBi3+exhibitno(orneglectable)electro-catalyticactivity.Additionally,therelationshipbetweenBiloadingandelectrochemicalactivityforV3+/V2+redoxcouplewasstudiedindetail.2wt%Bi-modifiedcarbonfelt(2%-BiCF)exhibitsthehighestelectrochemicalactivity.Usingitasnegativeelectrode,ahighenergyefficiency(EE)of79.0%canbeachievedatahighcurrentdensityof160mA/cm2,whichis5.5%higherthanthepristineone.Moreover,theelectrolyteutilizationratioisalsoincreasedbymorethan30%.Eventhecelloperatedat140mA/cm2forover300cycles,theEEcanreach80.9%withoutobviousfluctuationandattenuation,suggestingexcellentcatalyticactivityandelectrochemicalstabilityinVFBs.

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  • 简介:金属V作为贮氢材料具有良好的增压性能因而在ICF靶丸制备工艺中备受关注,但是金属V难活化,严重影响了其在增压材料方面的应用。为了改善金属V的活化性能,向金属V中掺杂少量的金属Ni以期达到对其改性和改善其贮氢性能的目的。

  • 标签: 吸氘性能 NI合金 制备工艺 贮氢材料 活化性能 ICF靶丸
  • 简介:全部的内部分区和(尖端)为~(12)在温度被计算直到6000KC~(16)O_2。用计算分区函数,我们生产ν_的线紧张~(12)的3乐队在几高温度的C~(16)O_2。结果证明计算的线紧张在在直到3000K的温度的HITRAN数据库的对那些的很好的同意,它在高温度为尖端和线紧张的计算提供强壮的支持。然后,计算被扩大推进高温度,和ν_的模仿的系列~(12)的3乐队在5000和6000K的C~(16)O_2被报导。

  • 标签: 二氧化碳 高温 光谱 配分函数 v3波段
  • 简介:Vanadiumalloys(V-Cr-Tiseries)areimportantcandidatematerialsforblanketcomponentsoffusionreactorsduetotheirlowactivationandhighstrengthatelevatedtemperatures.Low-temperatureirradiationembrittlementdeterminestheoperationtemperaturelimitofVanadiumalloysfortheapplicationtostructuralmaterialsoffusionreactorsirradiationresponseofvanadiumalloysneedstobeclarifiedfortheirapplication.Inthepresentstudy,specimensoftwoalloys(V-4Cr-4TiandV-5Cr-5Ti)wereirradiatedwithenergeticHeionsandheavyionstounderstandhardeningofthealloysduetoheliumaccumulationandcascadedamageproduction.

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  • 简介:Accordingtothewell-establishedlight-to-electricityconversiontheory,resonantexcitedcarriersinthequantumdotswillrelaxtothegroundstatesandcannotescapefromthequantumdotstoformphotocurrent,whichhavebeenobservedinquantumdotswithoutap–njunctionatanexternalbias.Here,weexperimentallyobservedmorethan88%oftheresonantlyexcitedphotocarriersescapingfromInAsquantumdotsembeddedinashort-circuitedp–njunctiontoformphotocurrent.Thephenomenoncannotbeexplainedbythermionicemission,tunnelingprocess,andintermediate-bandtheories.Anewmechanismissuggestedthatthephotocarriersescapedirectlyfromthequantumdotstoformphotocurrentratherthanrelaxtothegroundstateofquantumdotsinducedbyap–njunction.Thefindingisimportantforunderstandingthelow-dimensionalsemiconductorphysicsandapplicationsinsolarcellsandphotodiodedetectors.

  • 标签: 量子点结构 载流子输运 光电探测器 太阳能电池 光电转换原理 半导体物理学
  • 简介:Duetolowactivationcharacteristics,desirablehigh-temperaturestrength,goodresistancetoradiationdamageandusablefabricationproperties,vanadium(V)alloysareattractivecandidatestructuralmaterialsforfusionreactors[1].Irradiationinducedhardening/embrittlementatlowtemperatureisamajorproblemforthematerialsapplicationinfusionreactor[2].Inthisstudy,H/Heionswithvariousenergieswereusedtoirradiateapurevanadium(V)andaValloy(V-4Ti)toobtainadamageplateaufromsamplesurfacetothedepthof1.5m,asshowninFig.1[3].Thedetailsofirradiationparameters(energies,fluences)forHandHeionsareshowninTable1.NanoindentationwasperformedtoinvestigatethehardeningbehaviorofV-4TialloyandpureVunderirradiation.

  • 标签: NANOINDENTATION ALLOY IRRADIATED
  • 简介:Therearemoreandmorecountriestoakeanefforttothestudiesofvanadiumalloyforfusionapplication.NIFSinJapanhasrecentlydevelopedan80kgheatV4Cr4Tialloy(NIFS-heat2)aftertheproductionofa500kgscaleV4Cr4TiinU.S.severalyearsago.PropertyevaluationofthealloyhasbeenputintoaninternationalcollaborationprogramunderthecoordinationofIEA(InternationalEnergyAgency).SWIPhasjoinedthecollabrationonthehydrogenembrittlementresistanceevaluationofthealloyt.

  • 标签: 钒合金 氢脆变 阻抗 NIFS
  • 简介:Ti6Al4Visawidelyappliedinmedicalimplantssuchasbone,joint,andteethduetoitsexcellentmechanicalproperties,corrosionresistance,plasticityandthebiocompatibilityofthesurfaceoxide.However,thenativesurfaceoxidefilmisquitethin(about5nm)andtechniquessuchasmicroarcoxidation,plasmasprayedhydroxyapatitaeandplasmaimmersionionimplantationareusedtosynthesizethickersurfacetitaniumoxide.

  • 标签: 微弧氧化 生物活性 TI6A14V 氧化钛保护膜 金属材料