Release of Soil Nonexchangeable K by Organic Acids

(整期优先)网络出版时间:1993-03-13
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TheamountsofsoilnonexchangeableKextractedwith0.01mL/Loxalicacidandcitricacidsolutionsandthatwithboiling1mL/LHNO3fortenminuteswereremarkablysignificantlycorrelatedwitheachother,andtheamountextractedwiththeoxalicacidsolutionwashigherthanthatwiththecitricacidsolution.ThesoilnonexchangeableKreleasewascomprisedoftwofirst-orderkineticprocesses.ThefasteronewasascribedtotheinterlayerKinoutersphere,whilethesloweronetothatininnersphere.TherateconstantsofthesoilnonexchageableKweresignificantlycorrelatedwiththeamountsofnonexchangeableKextractedwithboiling1mL/LHNO3fortenminutes.Studyonthefitnessofdifferentkineticequationsindicatedthatthefirst-order,parabolicdiffusionandzero-orderequationscouldalldescribethereleaseofsoilnonexchangeableKwell,butElovichequationwasnotsuitabletodescribeit.