简介:Theabinitiogeneralizedgradientapproximation(GGA)+Ustudyofmultiferroic(La0.5Bi0.5)2FeCrO6inpnmastructureandferri-magneticorder,includingHubbardcorrections(U-4.1eV)fortransitionmetal/rareearthd-electronswith20atomscell,showsoptimumlocalmagneticmomentsof(Cr^3+,Fe^3+)equalto(-2.56,4.14)#Bandanidealspin-downbandgapof1.54eV.Tuned-bandgapLa-substituteddoubleoxideperovskitesBFCOshouldexhibitenhancedvisible-lightabsorptionandcarriermobility,thuscouldbeconvenientlightabsorbersandthenefficientalternativestowide-gapchalcopyriteabsorber-basedsolarcellsfailingtoachievehighestpowerconversionefficiencies,andevencompetewiththeirmetal-organichalideperovskitescounterparts.
简介:本文采用水热法在不同的条件下(不同温度、不同pH值、不同浓度的表面活性剂)制备了可见光催化剂Bi2WO6,同时也掺杂了Fe制备了Bi2WO6,并改变了原材料的配比,制备了Bi2O3-Bi2WO6。实验结果表明:Bi2WO6的禁带宽度在2.83eV,有良好的可见光催化性能。Bi2O3-Bi2WO6拓宽了禁带宽度,使得禁带宽度为3.05eV。催化剂的光催化活性和催化剂的晶型、颗粒的半径大小、比表面积的大小都密切相关。然而催化剂的形貌、粒径、比表面积又与制备条件密切相关,只有在特定形貌下,粒径小并且均匀的情况下的催化剂的催化活性才好。在酸性条件下由于抑制了硝酸铋的水解,从而制备的催化剂的催化活性优于在碱性条件下制备的催化剂。催化剂在降解罗丹明B的实验中,催化时的去乙基作用使得罗丹明B溶液的主峰发生蓝移,主峰由553nm移动到了495nm。催化剂的去乙基作用于只有在可见光的照射下才会发生,并且去乙基作用使得光催化降解反应的初速度加快。催化剂的吸附性能影响去乙基反应,吸附性能差的催化剂发生去乙基反应的速度也低。催化剂在降解染料时对染料有选择性,本实验所制备的催化剂对罗丹明B的降解效果高于对甲基橙的降解效果。
简介:摘要目前我国对电力的需求越来越大,这就需要增大电力系统的传输容量和传输距离。传统电缆由铜或铝制成,在传输过程中的线损约占15%。中国每年电力传输过程中的线损就超过数百亿千瓦时。与传统电缆相比,高温超导电缆具有容量大、损耗低、体积小、重量轻、以及系统可靠性高、节约资源、环境友好等优势。随着超导技术的发展,高温超导电缆与高温超导限流器被认为是最有可能首先在电力系统中商业应用的超导设备。世界上高温超导电缆的发展分成示范、样品和工业应用三个重要阶段,目前高温超导电缆已进入工业应用的初期发展阶段,对高温超导电缆长度的要求在不断增加、对耐压的要求在不断提高、对电流流通的要求在不断增大。
简介:摘要:本文简要概述了低温超导体研究与发展的历史,介绍了在低温超导理论发展过程中所发明与发现的零电阻现象,迈斯纳效应,约瑟夫森效应,伦敦方程,BCS理论等等。并根据现有知识对伦敦方程进行了简单的推导。
简介:Eu2+andDy3+codoped(Ca,Sr)7(SiO3)6Cl2yellowphosphorsweresuccessfullysynthesizedbyself-fluxmethod.Thestructure,morphologyandphotoluminescencepropertieswereinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andphotoluminescencespectra.Theas-preparedphosphorshowedabroademissionspectrumcenteredat550nmforEu2+single-dopedphosphor,whilelocatedat548–544nmfortheEu2+,Dy3+codopedsamplesunderexcitationat380nmlight.TheemissionintensitywasgreatlyimprovedwhenDy3+wasdopedintothe(Ca,Sr)7(SiO3)6Cl2:Eu2+system.Thecomposition-optimizedsamplewith3mol.%ofDy3+andconstant10mol.%ofEu2+exhibiteda220%PLenhancementcomparedtothephosphorwith10mol.%Eu2+single-doped.Meanwhile,itwasfoundthatthequantumefficiencyofphosphornamely(Ca,Sr)7(SiO3)6Cl2:3mol.%Dy3+,10mol.%Eu2+couldgetupto24.6%.Thesynthesizedyellow-emitting(Ca,Sr)7(SiO3)6Cl2:Dy3+,Eu2+isapromisingcandidateashigh-efficiencyyellowphosphorforNUV-excitedwhiteLEDs.
简介:KarstrocksfromtheHuanglongFormationexposedatthemarginoftheEasternSichuanBasincanbedividedintofourtypes:slightlycorroded,moderatelycorrodedporous,intenselycorrodedbrecciatedandintenselycorrodedandreplacedsecondarycalcickarsticrocks.Thecarbon,oxygenandstrontiumisotopecompositionsofthevariouskarstrocksareanalyzedsystematicallyandcomparedtorockswithoutkarstcorrosion.Theresultsindicatethat(1)theHuanglongFormationintheeasternSichuanBasinwasarestrictedbaysuppliedandcontrolledbyfreshwaterinwhichmudmicriteandmud-dolomicriteexhibitlowδ13Candδ18Ovaluesandhigh87Sr/86Srratios;(2)alltypesofkarsticrocksinthepaleokarstreservoirsoftheHuanglongFormationintheresearchareaareaffectedbyatmosphericfreshwaterwiththeδ13Candδ18Ovaluesand87Sr/86Srratiosintheoriginalformationapproachingthoseofatmosphericfreshwater,whichreflectsancienthydrologicalconditions,fluidproperties,isotopicsourceandthefractionationeffect;(3)theintenselycorrodedandreplacedsecondarylimestoneisaffectedbyavarietyofdiageneticfluids,oftenreflectedbyδ13Candδ18Ovalues,whilethe87Sr/86Srratiosexhibitthestrongdegreeofthecorrosion;(4)aftercomparingthe87Sr/86Srratiosofeachtypeofkarstrock,thediageneticfluidsaredeterminedtobemainlyatmosphericfreshwater,anddependingonthestrengthofcorrosion,andthelow87Sr/86Srratiofluidsinthelayerwillparticipateinthekarstprocess.Thecarbon,oxygen,andstrontiumisotopesofdifferentkarsticreservoirscanprovidemeaningfulgeochemicalinformationforforecastingandevaluatingthedevelopmentanddistributionrulesoftheHuanglongFormationatthemarginoftheeasternSichuanBasinintimeandspace.更多还原