简介:TheapplicationtechnologyusingBaosteelsteelslagpowderasanadmixtureofconcreteisthedevelopmentaldirectionofsteelslagrecyclingtreatmentandutilization,whichfullyreflectsthebasicfeaturesandgoodcompatibilityoftheover-calcinedclinkerofsteelslagresources.Itisbeneficialtofullyexploitthewaterhardeningcharacteristicandpotentialactivityofsteelslag,toreduceandcontroltheunstablefactors,suchasfreecalciumoxideandmagnesiumoxide,andtorealizehighvalue-addedapplicationsandexplorenewapplicationfields.
简介:Hydrogenthermalplasmajetwasemployedtopreparenano-sizedboronpowderwithhydrogenreductionofBCl3.Themaximumyieldofnano-sizedboronpowderswasabout50%withtheoperationalconditionsofH2/BCl3of4.5:1,totalfeedof4.9m3/h,andplasmapowerof25kW.ThesampleswereanalyzedbyX-raydiffraction(XRD),fieldemissionscanningelectronmicroscopy(FE-SEM),andinductivelycoupledplasma-massspectrometry(ICP-MS),inductivelycoupledplasma-atomicemissionspectrometry(ICP-AES),inductivecombustioninfraredabsorption(ICIA)andinfraredthermalconductivityofoxygenandnitrogenanalyzer(ITCA).Theresultsshowthattheboronpowdershavedifferentcrystalstructureswithhigherdispersionandpurity.Theaveragediameterisabout50nm,andthepurityis90.29%orso.Thisnewtechnologycanusesimpleprocesstoproducehighqualityboronpowders,andisfeasibleforindustrialproduction.
简介:Coprecipitationsupercriticalfluiddryingtechnologyhasbeenemployedtosynthesizecalcia-stabilizedzirconiaultrafinepowderwithlow-costinorganicsaltsasthestartingmaterials.Thesinteringbehaviorsofthesepowderswerealsoinvestigated.Theresultsshowedthatsupercriticalfluiddryingcouldeffectivelyalleviatethehardagglomerationofgrainsduringthegeldryingprocess,andthemorphologyofthepowderretainedthenetworktextureoftheoriginalgel.Theresultingparticleswerecharacterizedbysmallparticlesize(5~20nm),bettermonodispersityandhighsurfacearea,whichgaverisetohighactivityandsinterability.Consequently,thesepowderscouldreadilybecompactedintothedesiredshapeandtheirdensificationcouldbecarriedoutinshortertimeandatlowertemperatures.Forinstance,nanometer-sizedpowdercalcinedat600℃for2hcouldbecold-pressedintoagreenbodyandsinteredat1100°for0.5htoattainadensebodywithbulkdensityof5.9718g/cm3andspecificporevolumeof0.0008cm3/g.
简介:Becauseoftheradioactivityandtoxicnatureofnuclearmaterials,theircontainmentwithinoxidematrices,encasedinsealedcontainers,hasbeenproposedasasuitablemeansforstorageandtransportation.However,containerfailuresbecauseofcracksorsmallorificespresentamajorleakageriskfornuclearmaterials,consequentlyposingasignificanthazardtotheenvironmentandhumanbeings.Inthisstudy,terbiumoxidepowderwasusedasanuclearmaterialrepresentativetoexaminetheleakageofnuclearmaterialpowderthroughorificeslocatedatthebaseofapressurecontainer.Thedependenceoftheorificediameter,thepowderlayerthickness,andtheinternalpressureofthecontainerontheleakagemechanismandamountwasexamined.Asimplifiedmodelcorrelatingthedependenceoftheabove-mentionedparameterstodeterminetheutmostleakageamountwasalsodevelopedbasedonthepresentresults.Theleakageofthenuclearmaterialpowderwasassessedbymeasuringitsconcentrationusinganopticalparticlecounter.Thediameteroftheorificedeterminedthepowderleakagemechanism,whichinturninfluencedtheamountofleakageproduced.Comparisonstudiesshowedthatunlikethechangesinthedifferentialpressure,thevolumeofthecontainerhaslittleeffectontheleakageamount.Undersufficientlyhighinternalpressures,theoxidepowdercanbereleasedasafineaerosol.Theworkisnotonlycrucialfromthenuclearsafetyaspect,butisalsobeneficialforthesafeapplicationofpowderandnanoparticles.
简介:铝泡沫三明治被rolling-bonding/powder准备在脸表/粉末和粉末密度的契约力量上滚动的冶金的起泡沫技术,和效果被学习。而且,起泡沫的代理人,TiH2,热被对待,Mg的某个数量在一次尝试被增加进粉末理解泡沫的稳定性和一致性怎么被改进。试验性的结果证明有理想的质量的起泡沫的先锋被结合转动的过程获得。当卷减小是67%时,粉末的一致性活动范围到99.87%。在整个脸表/核心层粉末和粉末的变丑特征结合的考虑,卷减小的最佳是60%70%。裂缝和排水被起泡沫的代理人TiH2的热处理和Mg的某个数量的增加在起泡沫期间禁止。TiH2的最佳热处理方法是在450点保存1个小时的那热???眶?嘠伲‵???ㄠ‵吗?
简介:Theblastresistanceofstructuresusedinbuildingsneedstobeinvestigatedduetotheincreasedthreatofaterroristattack.ThedamagedonebyCompositionBorPowergeltosteelfibrereinforcedreactivepowderconcrete(SFRPC)panelsandordinaryreinforcedconcrete(RC)panelsofequivalentstaticflexuralstrengthiscompared.A0.5kgchargewasdetonatedatadistanceof0.1mfromthe1.3m×1.0m×0.1m(thick)panels,whichweresimplysupportedandspaning1.3m.Dynamicdisplacementmeasurements,high-speedvideorecordingandvisualexaminationofthepanelsforspallandbreachwereundertaken.TheSFRPCpanelswithstoodthebarechargeblastbetterthanthereinforcedordinaryconcretepanels.Neithertypeofpanelwasbreachedusinga0.5kgcharge.TheRCpanelexhibitedmorespallingwhenCompositionBwasused.UndersuccessiveCompositionBloadingconditions,theRCpanelwasbreached.IncomparisontheSFRPCpanelwasnotbreached.ExposuretofragmentingchargeloadingconditionsconfirmedtheseperformancedifferencesbetweentheSFRPCpanelandthereinforcedordinaryconcretepanel.
简介:InordertoobtainultrafineNd-Fe-Bpowder,aspray-driedprecursorwastreatedbyreduction-diffusion(R/D)process.And,unliketheconventionalR/Dprocess,calciumreductionthatisacrucialstepfortheformationofNd2Fe14BwasperformedwithoutconglomeratingtheprecursorwithCapowder.Byadoptingthismodifiedprocess,itispossibletosynthesizethehardmagneticNd2Fe14Batthereactiontemperatureaslowas850℃.TheaveragesizeofNd2Fe14Bparticlesthatareuniformlydistributedintheoptimallytreatedpowderwas<<1μm.MostNd2Fe14BparticleswereenclosedwiththinlayersofNd-richphase.TypicalmagneticpropertiesofsuchpowderwithouteliminatingimpurityCaOwereiHc=~5.9kOe,Br=~5.5kG,and(BH)max=~6MGOe.
简介:Inaflowinjectionseparationandpreconcentrationsystemincorporatingamicrocolumn,theadsorptionbehavior(effectofpH,kineticadsorptioncapacity)ofmetalionsCu^2+,Cr^3+,Mn^2+,Ni^2+,La^3+,Eu^3+,Ga^3+,Mo(Ⅵ)andW(Ⅵ)onTiO2owderwithdifferentcrystalstructureandparticlediameterwasstudiedandcompared.Inaddition,theechanismoftheadsorptionofmetalionsonTiO2owderwasexplored.TheresultsshowthatcrystaltructureandparticlediameteroftheTi02powderwillefinitelyaffecttheadsorptioncapacityofmetalsont.
简介:AhypereutecticAl-Sialloypowderwaspreparedbyultrasonicgasatomizationprocess.Themorphologies,microstructureandphaseconstituentofthealloypowderwerestudied.TheresultsshowedthatpowderofthealloywasveryfineanditsrnicrostructurewasmainlyconsistedofSicrystalsplusintermetalliccompoundAl9FeSi3,whichwere.veryfineanduniformlydistributed.
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简介:TheinfluenceofthreedifferentAl2O3powderonself-flowingaluminacastablewasstudied.MaximumcompactionofsamplewascomputedbyAndresenEquation.TheresultshowedthattheAl2O3powder,whichhasmuchsmallerparticlesize,couldimprovethemicrostructureandthemechanicalpropertiesofcastableunderroomtemperatureandhightemperature.Withthesamepowdersize,theroomtemperaturestrengthofthecastableaddedwithAl2O3powderproPertiesofwhichwerealteredbyaddingmineralizingagent,washigherthanthatofthecastableaddedwithcommonAl2O3powder,buttheflowabilityofthesethreedifferentcastablewasalmostthesame.
简介:Epoxy/graphenenanoplatelets(GNP)粉末涂层用GNP和融化混合挤出方法的超声的predispersion被制作。epoxy/GNPs粉末涂层的等温的治好动力学借助于即时Fourier变换被监视有一个加热房间的红外线的光谱学(英尺红外)。epoxy/GNPs的机械性质治好涂层被调查了,由评估他们有扫描在three-point-bending测试以后的电子显微镜学(FE-SEM)的地排放的破裂表面。epoxy/GNPs的热稳定性治好涂层被thermo-gravimetric分析(TGA)学习。等温的治好动力学结果证明GNP不影响自动催化的反应机制,但是在玩的1.0wt%添加剂下面装载GNP在治好epoxy/GNPs粉末涂层的一个提示角色。破裂紧张,破裂坚韧和epoxy/GNPs的影响抵抗治好在装载的GNP(1wt%)的底层戏剧性地增加的涂层,显示GNP能改进epoxy/GNPs粉末涂层的坚韧。从破裂表面的FE-SEM研究,而且,epoxy/GNPs的可能的韧化机制治好涂层被建议。TGA结果证明GNP的加入改进了治好的涂层的热稳定性。因此,GNP修改了环氧基树脂能是一条有效途径与改进他们的热稳定性一起韧化环氧基树脂粉末涂层。
简介:Anisotropicpowderwaspreparedwithprecursor(NdDy)-(FeCoNbCu)-Bsinteredmagnetsbyhydrogendecrepitation,desorption,andsubsequentannealingtreatment.Thehydrogendesorptionwasperformedinmagneticfieldsof0,1,3,and5T.Theorientationoftetragonalphasegrainsofthepowderwasevaluatedfromthehysteresisloopsmeasuredbyextractionmagnetometer.Residualhydrogencontentofthepowderwasevaluatedbythermal-magneticanalysis.ThepowderwithHcj,Br,and(BH)maxof1138kA·m-1,1.029T,and172.5kJ·m-3,respectively,wasachievedundertheconditionofthemagneticfieldof3T.Magneticpropertiesofthepowder,especially,theremanenceofthepowder,areenhanceduponmagneticfields,whichisduetobetterorientationofpowderparticlesandlessresidualhydrogeninthepowderresultedfromthemagneticfieldduringthehydrogendesorptionprocess.
简介:MoltensaltsynthesisofMgAl2O4powderfromindustrialaluminaandlightcalcinedMgOinKCl,LiCl,andKCl-LiClmedia,andtheinfluenceofKFat500-1000℃wereinvestigated.SynthesizedpowderswerecharacterizedbymeansofXRD,laserparticleanalyzer,andSEM,andthesynthesismechanismofMgAl2O4wasdiscussedaswell.Theresultsshowthat(1)themoltensaltcomposite(KCl-LiCl)ismorefavorableforthesynthesisofMgAl2O4thansinglemoltensalt(LiClorKCl),andLiClismorefavorablethanKCl;(2)KFcanacceleratetheformationofMgAl2O4anddecreaseitsformingtemperature;(3)synthesisofMgAl2O4powderinthemoltensaltswithoutKFiscontrolledby'template-growth'mechanism,butinthemoltensaltswithKF,itiscontrolledby'template-growth'and'dissolution-precipitation'mechanism.
简介:有从30~80nm的尺寸的Fe3O4nanoparticles被湿milling铁粉末在一家行星的球工厂综合。阶段作文和同样综合的产品的形态学被X光检查衍射(XRD)测量,扫描电子显微镜学(SEM)和传播电子显微镜学(TEM)。NanosizedFe3O4粒子被湿milling准备金属性的铁粉末(?200网孔,99%)在与不锈钢装备的一家行星的球工厂,使用的小瓶与50:1并且以300rpm的旋转速度的ball-to-powder团比率在提取的水下面熨球。在这个方法的铁球的使用在Fe3O4formation起了一个关键作用。现在的技术简单,这个过程是容易的执行。
简介:Auranylcompound,K4UO2(CO3)3hasbeencharacterizedbypowderX-raydiffractionmethod.M.W.=606.46,monoclinic,C2/c(No.15),a=1.0240(7),b=0.9198(4),c=1.2222(12)nm,β=95.12(4)°,V=1.1466(5)nm3,Z=4,Dm=3.468g/cm3,Dc=3.513g/cm,λ(CuKα1)=O.1540598nm,T=298K.ThestructurewassolvedbyheavyatommethodandFouriersynthesis,andrefinedbyfull-matrixleast-squaresmethodtoR=0.1185for275reflections.Theuranium(Ⅵ)atomisinaneight-coordinatedistortedhexagonal-bipyramidalenvironmentwithcreasyfanshape.Thelinearuranylgroupapproachestoperpendiculartotheequatorialplaneinwhichthreecarbonategroupsarechelated.U(Ⅵ)hastwolinearoxygenatomsclosertoit(U-O=0.1767(5)nm)thansixotherneighbours(U-Orangingfrom0.2516to0.2568nm).Thedistancesbetweencarbonatomsanduncoordinatedoxygenatomsare0.122(1)and0.123(1)nm,whicharedistinctlydifferentfromthosebetweencarbonandcoordinatedoxygenatoms(mean0.134(6)nm).Thisfactrevealsthenon-eq-uivalenceofoneoxygenatomtotheothertwoineachcarbonate.InK4UO2(CO3)3,theO-Odis-tancefortheadjacentcarbonategroupsis0.2794(4)nmapproachingtothesumofVanderWaalsradiioftwooxygenatoms.TheK-Odistancesvarybetween0.2667and0.3131nm,andeachanionisimmediatelysurroundedbysixpotassiumions,onlyfourofwhichcanbeconsideredtobelongtothesamestructuralformulaunit,andtheyaresymmetricallylocatedaboveandbelowtheequatorialplane.