简介:鄂尔多斯盆地中东部山西组可划分为3个沉积层序,其中SQ8(山2段)可划分为低位、湖侵及高位体系域,主要砂体发育于低位体系域。SQ8—LST可细分为3个进积型准层序组,其砂体呈进积式向湖盆推进,自下而上分为L1,L2和L3准层序组,砂体厚度由薄变厚,分布面积由小变大。L1准层序组仅在研究区西北部发育一支近南北向展布的主砂带,砂岩厚2~10m,砂带宽10~15km,延伸约100km;L2,L3准层序组的砂体分布格局相似,砂岩厚度为4~20m,发育5~6支近南北向、北东向展布的砂带,砂带宽10~25km,延伸200~230km。L1准层序组为大规模海退之后的初始充填沉积,其砂岩成分复杂、分选差,储层物性相对较差,而向上至L2,L3准层序组,储层物性明显变好。有利的储集砂体为发育于低位体系域中上部准层序组的三角洲平原分流河道、前缘水下分流河道及河口坝砂体。三角洲前缘砂体物性略优于三角洲平原砂体,边滩砂体物性较差。
简介:以2,3-二氯萘醌与氨气为原料,甲醇作溶剂,制备了2-氨基-3-氯-1,4-茶醌。考察了反应条件对产品收率的影响,得到最件工艺条件:在二氯萘醌用量为0.1mol,氨与二氯萘醌的物质的量比为6,氨甲醇溶液含量15%~17%,反应温度20~25℃,反应时间4h,产品收率可达96%。
简介:Inthispaper,2-isopropylnaphthalenehasbeensynthesizedbythereactionofnaphthaleneandisopropylbromide,usingtriethylaminehydrochloride-aluminumchlorideionicliquidasthecatalyst.Theeffectofthecatalystcomposition,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratioofthereagentsonthe2-isopropylnaphthaleneyieldwassystematicallyinvestigated.Theoptimalreactionconditionscover:anAlCl3toEt3NHClratioof2.0,areactiontimeof3h,areactiontemperatureof15.0℃,avolumefractionofionicliquidtothemixture(isopropylbromide,n-dodecaneandn-hexane)of9%,andanaphthalene/isopropylbromidemolarratioof4.0.Undertheoptimalreactionconditions,theconversionofisopropylbromidereached98%andtheselectivityof2-isopropylnaphthalenewasequalto80%.ThetestresultsverifiedgoodcatalyticactivityuponusingEt3NHCl-AlCl3ionicliquidasthecatalystforalkylationofnaphthalenewithisopropylbromide.Theactivityoftheionicliquidremainsunchangedafterithasbeenrecycledfor4times.
简介:AninnovativeapproachtoH2Scapturehasbeendevelopedusingseveralmetal-basedionicliquids([Bmim]Cl·CuCl2,[Bmim]Cl·FeCl3,[Bmim]Cl·ZnCl2,[Bmim]Br·CuCl2,and[Bmim]Br·FeCl3)immobilizedonthesol-gelderivedsilica,whichissuperiortopurelyviscousionicliquidwithacruciallimitofhightemperature,lowmasstransferrate,andmassloss.TheadsorbentswerecharacterizedbytheFouriertransforminfraredspectrometer,transmissionelectronmicroscope,N2adsorption/desorption,X-rayphotoelectronspectroscopy,andthermalanalysistechniques.TheeffectsofthemetalandhalogeninIL,theloadingamountofIL,andtheadsorptiontemperaturewerestudiedbydynamicadsorptionexperimentsatagasflowrateof100mL/min.TheH2Sadsorptionresultshaveshowedthattheoptimaladsorbentandadsorptiontemperatureare5%[Bmim]Cl·CuCl2/silicageland20-50℃,respectively.H2Scanbecapturedandoxidizedtoelementalsulfur,and[Bmim]Cl·CuCl2/silicagelcanbereadilyregeneratedbyair.TheexcellentefficiencyofH2Sremovalmaybeattributedtotheformationofnano-scaledandhigh-concentration[Bmim]Cl·CuCl2confinedinsilicagel,indicatingthattheimmobilizationof[Bmim]Cl·CuCl2onthesol-gelderivedsilicacanbeusedforH2Sremovalpromisingly.
简介:核磁共振录井测量过程中,t2弛豫谱是重要的参数,其中包含着孔隙度、可动流体、含油饱和度等储集层物性信息。根据t2弛豫谱分析原理着重介绍了t2弛豫谱形态在不同性质储集层中的特征,列举了油气水层的典型谱图特征:油层的谱图特征为弛豫时间较长,右半部分谱图较发育,可动流体值高、含油饱和度高;水层的谱图特征为可动流体值较高,油信号谱峰低、孔隙中以可动水为主;油水同层的谱图特征为油信号谱峰与水层相比较高,但大部分孔隙空间被可动水充填,含油饱和度一般为10%~40%;干层的谱图特征为低孔隙度、低渗透率、低可动流体、低含油饱和度。进而通过实例分析,说明了t2弛豫谱在储集层评价和油气水层解释中的重要作用。