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  • 简介:Inthisarticle,theFCCdieselfuelischemicallytreatedwithGZreagent.Theexistentgum,insolublesafteroxidation,andiodinemunberaregreatlyreducedafterchermicaltreatment.Thismethodhasagoodeffectandissimple.Thismethodischaracterizedbyhighrecoveryrateoffuel(>99.7?andlowcost.Thepropertyofthemixtureofchemicallytreateddieselfuelwithstraight-rundieselfuelcanmeettherequirementsofnationalstandardGB252-2000.Thecolorandoxidationstabilityofthemixedfuelafterhavingbeenstoredforthreemonthswerestilllowerthanthevaluesspecifiedinthenationalstandard.

  • 标签: FCC柴油燃料 燃料质量 GZ试剂 化学精炼 非加氢精炼法 改进
  • 简介:Investigationsonthepyrolysisandkineticbehaviorsduringpyrolysisoffossilfuelsamples,suchascoal,arefundamentalfordevelopingtherelatedtechnologyandpracticalapplication.Inthiswork,pyrolysisbehaviorandkineticsinthepyrolysisprocessofacoalsamplewereinvestigatedbythethermogravimetricanalyzerataheatingrateof10,40,70,100,200,and500°C/min,respectively.ThepyrolysisprocesscouldbedividedintofourstagesaccordingtotheTG/DTGcurves.Thefirststagewasmainlyattributedtotheremovalofvolatiles,andthesecondpeakwasthepolycondensationreactionbetweenthevolatilecomponents.Itwasfoundthatmorevolatilescouldbereleasedfromcoalduringpyrolysisathigherheatingrateandthehigherpyrolysistemperaturewasnecessaryforarapidpyrolysisprocess.Kineticanalysisrevealedthatboththemodel-free(KASandFWO)andtheCoats-Redfernmethodsweresuitabletodescribingthepyrolysisprocess,andthevariationofactivationenergy(E)withthetwotypesofkineticmodelswasconsistentduringthewholepyrolysisprocess.Furthermore,theheatingratedidnotalterthereactionsequenceofthewholepyrolysisprocess,buthigherheatingratecouldmaketheEvalueoftheinitialpyrolysisstagesmaller.

  • 标签: PYROLYSIS BEHAVIOR KINETIC analysis TG/DTG CURVES
  • 简介:  Inordertoactivelyutilizethenon-traditionalresourcesandreducethedependenceofchemicalindustryoncrudeoil,theMinistryofScienceandTechnologyhasincludedtheproject"Keytechnologyformanufactureofmassivechemicalsviaanon-oilbasedroute"inthe"NationalEleventhFive-YearScienceandTechnologySupportingPlan"andisnowcallingforapplicationforrelevantresearchprojects.……

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  • 简介:在花的催化裂开的催化剂上扔的焦炭的氧化经由非等温的氧化工具与煤和煤字符的相比,即thermal-gravimetric分析(TGA)和微分热分析(DTA)。氧化运动参数被模型试穿方法进一步调查。测试结果证明花的催化剂的氧化是一个相当温和的过程,当煤和煤字符在氧化期间经历了锋利的重量损失时。为氧化的开始和结束的温度在下列顺序增加了:煤

  • 标签: 催化裂解催化剂 非等温氧化 废催化剂 煤氧化 反应动力学参数 反应模型
  • 简介:Ahigh-density,high-fluxcirculatingfluidizedbed(CFB)riser(100mminIDand10.614minheight)wasappliedinawiderangeofoperatingconditions(withsolidfluxesupto400kg/m2sandsuperficialgasvelocitiesupto12m/s)toexamineitsradialnon-uniformitydynamics.Thesolidsholdupwasdeterminedthroughtheuseofafiber-opticprobeat11axiallevels.Theresultsindicatedthatunderalloperatingconditions,thehighsuperficialgasvelocityandlowsolidfluxesmaintainedalowradialnon-uniformityindex(RNI).Thehigh-density/fluxCFBriserhadseveraluniquecharacteristics,sothatthepeakoftheradialsolidsholdupprofileoccurredatapositionwithr/R=0.8.TheRNIandsolidsholdupatthecross-sectionalpositionhadagoodlogarithmicrelationshipatthelow-densitycondition(withameansolidsholdupof<0.2),andtheRNIdecreasedwhenthemeansolidsholdupexceeded0.2.InvestigationofthedynamicsofstratifiedinjectionrevealedthatthefeedratiohadanimportanteffectonGsandonsolidsholdupdistribution.Anovel"<"shapedaxialsolidsholdupprofilewasfound.Gsdecreasedsharplywhentheup-flowfeedratioexceeded0.5,andRNIwaslowestwhentheup-flowfeedratiowas1.

  • 标签: 气固循环流化床 高密度 高通量 均匀性指标 径向 颗粒浓度分布