简介:ItiswellknownthatthephotocatalyticactivityofTiO2thinfilmsstronglydependsonthepreparingmethodsandpost-treatmentconditions,sincetheyhaveadecisiveinfluenceonthechemicalandphysicalpropertiesofTiO2thinfilms.Therefore,itisnecessarytoelucidatetheinfluenceofthepreparationprocessandpost-treatmentconditionsonthephotocatalyticactivityandsurfacemicrostructuresofthefilms.ThisreviewdealswiththepreparationofTiO2thinfilmphotocatalystsbywet-chemicalmethods(suchassol-gel,reversemicellarandliquidphasedeposition)andthecomparisonofvariouspreparationmethodsaswellastheiradvantageanddisadvantage.Furthermore,itisdiscussedthattheadvancementofphotocatalyticactivity,super-hydrophilicityandbactericidalactivityofTiO2thinfilmphotocatalystinrecentyears.
简介:TheK2Ti4O9whiskerswerechosenforthecatalystcarrier,TiO2/potassiumtitanatephotocatalystwaspreparedbySol-gelmethod.TheproductwascharacteratedbyX-raydiffractionandSEM.EDSshowsthat,themainpeckincludedTi,O,andKinpotassiumtitanatewhisker.ThemainpeakofKdisappearedandthepeaksofTi,Ostayedafterwhiskerwascovered.ItdirectedthatthesurfaceofsamplewascoveredbyTiO2.XRDshowsthatdiffractionpeakappeared,whichwascorrespondedtothepeakofanataseTiO2.Inthereactiondeviceofphotochemistry,usingmiddle-pressuremercurylampasillumination,rhodamineBassimulantpollutant,thephotocatalyticperformanceofTiO2/potassiumtitanatewasstudied.Underthesameconditions,thelowerpH,thelargerilluminance,thehighertemperature,thegreateraerationquantumandthelowerinitialconcentrationofrhodamineB,thehigherdecolorationratewasgot.Underourexperimentconditions:pH6,theilluminanceof250W,thetemperatureof313K,andtheaerationquantumof2.0L/min.WhentheconcentrationofrhodamineBwas8mg/LThephotocatalystofTiO2/potassiumtitanatewas0.01g/L.ThedecolorationrateofTiO2/potassiumtitanatedealtwiththerhodamineBreachover95%in160min,andcomparewithTiO2,thedecolorationrateofrhodamineBwasimproved0.50~1.91multiple.TiO2/potassiumtitanatecanbeusedtotreatmentofdyewastewater.
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简介:Inordertodeepentheunderstandingoftherelationshipbetweenfundamentalproperties(including:microstructureandcomposition)andphotocatalyticperformance,fourbismuthatecompounds,including:LiBiO3,NaBiO3,KBiO3,andAgBiO3,areregardedasresearchexamplesinthepresentwork,becausetheyhaveparticularcrystalstructuresandsimilarcompositions.Usingdensityfunctionaltheorycalculations,theirstructural,electronic,andopticalpropertiesareinvestigatedandcomparedsystematically.Firstofall,thecalculatedresultsofcrystalstructuresandopticalpropertiesareinagreementwithavailablepublishedexperimentaldata.Basedonthecalculatedresults,itisfoundthatthetunneledorlayeredmicro-structuralpropertiesleadtothestrongerinteractionbetweenbismuthandoxygen,andtheweakerinteractionbetweenalkaline-earthmetaland[BiO6]octahedron,resultinginthefeatureofmulti-bandgapsinthecasesofLiBiO3,NaBiO3,andKBiO3.ThisconclusionissupportedbythecaseofAgBiO3,inwhichthefeatureofmulti-bandgapsdisappears,duetothestrongerinteractionbetweenthenoblemetaland[BiO6]octahedron.Thesepropertieshavesignificantadvantagesinthephotocatalyticperformance:absorbinglowenergyphotons,rapidlytransferringenergycarriers.Furthermore,thefeaturesofelectronicstructuresofbismuthatecompoundsarewellreflectedbytheabsorptionspectra,whichcouldbeconfirmedbyexperimentalmeasurementsinpractice.Combinedwiththecalculatedresults,itcouldbeconsideredthatthecrystalstructuresandcompositionsofthephotocatalystdeterminetheelectronicstructuresandopticalproperties,andsubsequentlydeterminethecorrespondingphotocatalyticperformance.Thus,anovelBi-basedphotocatalystdrivenbyvisible-lightcouldbedesignedbyutilizingspecificcompositionstoformfavorableelectronicstructuresorspecificmicro-structurestoformabeneficialchannelforenergycarriers.
简介:我们的以前的研究建议氧化还原作用反应独立继续了TiO的特定的暴露的水晶脸<潜水艇class=“a-plus-plus”>2nanoparticles。TiO上的金属或金属氧化物的地点选择的免职<潜水艇class=“a-plus-plus”>特定的暴露的水晶成功地面对的2用唯一的反应性质继续了TiO的表面<潜水艇class=“a-plus-plus”>在photoexcitation下面的2nanoparticles。控制形状的brookite和金红石TiO的photocatalytic活动的显著改进<潜水艇class=“a-plus-plus”>有Fe的修正的2nanorods<啜class=“a-plus-plus”>3+混合物在可见的光下面被观察。TiO的暴露的水晶脸上的水晶脸选择的金属混合物修正<潜水艇class=“a-plus-plus”>有brookite和金红石阶段的2nanorods成功地被准备。Brookite和金红石TiO地点选择的修正与金属混合物准备的2nanorods应该是理想的可见光的应答的TiO因为背电子的显著抑制,2光催化剂从TiO转2到TiO的表面上的氧化金属混合物有brookite或金红石阶段的2nanorod。在这份报纸,暴露的水晶的发展控制脸的TiO<潜水艇class=“a-plus-plus”>有金红石和brookite阶段的2nanorods被描述。获得的金红石和brookiteTiO<潜水艇class=“a-plus-plus”>2nanorod,与锐钛矿罚款粒子(ST-01)的photocatalytic活动相比为有机化合物的降级显示出显著地高的活动,是为在日本的环境清除的最活跃的商业地可得到的光催化剂之一。为控制形态学的金红石和brookiteTiO的可见光的应答的处理的技术<潜水艇class=“a-plus-plus”>由水晶的2nanorodsFe的脸选择的修正<啜class=“a-plus-plus”>3+
简介:Inthepresentstudy,weinvestigatedtheeffectofceriumanderbiumdopingofthezirconiumdioxidematrix.Wesynthesizeddopedsamplesusinghydrothermalprocess.Theamountsofdopantusedwere0.5%,1%and5%molar(rareearthoxideoverzirconiumdioxide)respectively.ThesampleshavebeenstudiedviaX-rayDiffractionmeasurementsforthestructuralcharacterization.UVvisiblediffusereflectancewasusedfortheopticalanalysis,Brunauer-Emmett-Teller(BET)modelforthemeasurementofthesurfacearea.Finallythesampleshavebeenanalysedviaelectronparamagneticresonance(EPR)fortheelectroniccharacterization.Thenwetestedthenewsynthetizedmaterialstodeterminetheirphotocatalyticactivityinthereactionofdegradationofmethyleneblueperformedunderirradiationbydiodes(LEDs)emittingexclusivelyvisiblelight.
简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.