学科分类
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3 个结果
  • 简介:基于的二naphthalimide的技术性质分散尼龙6上的染料和聚酯纤维面对脲被调查。基于的二naphthalimide驱散染料被综合。染料被净化然后充分描绘了使用1H-NMR,FTIR和融化的点分析。染料的分散在水里被准备并且在尼龙6上适用并且宠物纤维。染料在底层上提供了好逐渐增加性质。为了增加,染底层的吸附,脲被增加进dyebath。由增加脲,聚酯的染料吸附显著地被增加,当尼龙6的增加是不显著的时。染料在底层上显示出好迅速性质。

  • 标签: 染料合成 PET纤维 尿素合成 聚酯纤维 技术性能 尼龙6
  • 简介:One-stepreactioncompatibilizedmicrofibrillarreinforcediPP/PETblends(CMRB)weresuccessfullypreparedthrougha'slitextrusion-hotstretching-quenching'process.CrystallizationbehaviorandmorphologyofCMRBweresystematicallyinvestigated.Scanningelectronicmicroscopy(SEM)observationsshowedblurryinterfaceofcompatibilizedcommonblend(CCB).ThecrystallizationbehaviorofneatiPP,CCB,microfibrillarreinforcediPP/PETblend(MRB)andCMRBwasinvestigatedbydifferentialscanningcalorimetry(DSC)andpolarizedopticalmicroscopy(POM).TheincreaseofcrystallizationtemperatureandcrystallizationrateduringnonisothermalcrystallizationprocessindicatedbothPETparticlesandmicrofibrilscouldserveasnucleatingagentsandPETmicrofibrilsexhibitedhigherheterogeneousnucleationability,whichwerealsovividlyrevealedbyresultsofPOM.ComparedwithMRBsample,CMRBsamplehaslowercrystallizationtemperatureduetoexistenceofPETmicrofibrilswithsmalleraspectratioandwiderdistribution.Inaddition,sinceinsitucompatibilizertendstostayintheinterphase,itcouldalsohinderthediffusionofiPPmoleculestothesurfaceofPETphase,leadingtodecreaseofcrystallizationrate.Two-dimensionalwide-angleX-raydiffraction(2D-WAXD)waspreformedtocharacterizethecrystallinestructureofthesamplesbyinjectionmolding,anditwasfoundthatwell-developedPETmicrofibrilscontainedinMRBsamplepromotedformationofβ-phaseofiPP.

  • 标签: 聚酯微纤维 聚对苯二甲酸乙二酯 等规聚丙烯 结晶行为 反应增容 PET