简介:LowcostsiliconcarbonnanometerpowderwassynthesizedbycarbothermalreductionmethodwithnanometerSiO2andcarbonasrawmaterial.Itssynthesisthermodynamicswerediscussed.TheinfluenceofLaonTG-DSCcurvewasalsoanalyzed.ItindicatedthatthesynthesisprocessofSiCpowderhadtwosteps.InthefirststeptwomedialproductionsofSiOgandCOgformed,andinthesecondstep,β-SiCwasfinallysynthesized.After0.3%Laadded,atthefirststep,theinitiatoryformingtemperatureofproducingSiO(g)andCO(g)declinedfrom1351.4to1250.9℃,andthethermalactivationenergydecreasedfrom223.6to34.7J·g-1;atthesecondsteptheinitiatoryformingtemperatureofsynthesizingβ-SiCpowderdeclinedfrom1526.5to1357.8℃,andthethermalactivationenergydecreasedfrom693.7to295.7J·g-1.WithoutLaadded,thebestsynthesistechnologyforβ-SiCpowderwas1550℃for120min,averagepowderdiameterwasbiggerabout150nm.WithLaadded,thebestsynthesistechnologywas1500℃for120min,averagepowderdiameterwasabout100nm.
简介:WetheoreticallyinvestigatednegativeentropySofbiopolymerwhichpassesthroughananometerpore(suchasα-hemolysin),especiallyenteringprocessandescapingprocess,onthebasisofwhichwealsostudiedbiopolymerentering-poretimeτent,biopolymerenteringmeanvelocityvent,biopolymerescaping-poretimeτesc,andbiopolymerescapingmeanvelocityvesc,respectively.Ourresultsillustratethattheenteringandescapingprocessesofbiopolymerdependonitsnegativeentropy,andenteringprocessismoredifficultthanescapingprocessforbiopolymertranslocation.Thistremendousdifferencebetweenthetwoprocesseswillofferausefulengineeringhintforsinglemacromoleculeidentification.
简介:TheencapsulationofstearicacidcoatednanometerCaCO3byapolystyrene(PS)networkviaemulsionpolymerizationisdescribed,whereγ-methacryloxypropyltrimethoxysilane(MPS)wasusedasanefficientcrosslinker.TheimportantfactorssuchasthetypeandamountofsurfactantandinitiatorandthecontentofCaCO3areinvestigatedaswellastheroleofMPS.IthasbeenshownthatlittlePSwasextractablewithonly0.6wt%ofMPS(relativetostyrene).Thecationicsurfactantcetyltrimethylammoniumbromide(CTAB)provedmoreeffectivethantheanionicsurfactantsodiumdodecylsulfonate(SDS).Theyieldrises,particlesbecomesmallerandsizedistributionbroadenswithincreasedamountofCTAB.Itisalsofoundthateither2,2′-azobis(isobutyronitrile)(AIBN)orammoniumpersulfate(APS)issuitableforattaininghighmonomerconversion.WithincreasedamountofCaCO3,theencapsulationratiocanbevariedfrom17.9to3.6,whilemonomerconversionandyielddecreaseslightly.FT-IRspectraoftheproductsafterextractionindicatetightencapsulationbetweenPSandCaCO3,andTEMphotographsofcompositeparticleswithwell-definedcore-shellstructuregivedirectevidenceofencapsulation.
简介: Thebonecompositewasproducedbybiomimeticsynthesis.Itshowssomefeaturesofnaturalboneinbothcompositionandmicrostructure.Andthecollagenmolecularsandthenano-crystalhydroxyapatiteassembleintoultrastructuresimilartonaturalbone.Itpossessesporousstructurewithporosityfrom100μmto500μmaftermixedwithPLA(polylacticacid). ……
简介:这份报纸论述nanometer-CeO2的影响的比较研究(tribological和锂的润滑性质上的nano-CeO2)和温度润滑。nanocrystals的形态学和结构分别地借助于传播电子显微镜学(TEM)和X光检查衍射(XRD)被描绘。磨擦并且穿测试在磨擦上被进行并且穿测试者。有nanometer-CeO2的增加的锂油脂举办的结果表演更好减少磨擦并且反穿性能比基础油脂的。当在油脂的添加剂是0.6时?wt%,磨擦系数(COF)并且穿疤直径(WSD)在28%和13%减少分别地与基础油脂作比较。有0.6的基础油脂和油脂?wt%nanometer-CeO2拥有最低平均COF并且在50点穿宽度?????|
简介:不同尺寸的喷雾器被一个安德森空气刺绣花样收集观察黑碳(BC)的详细形态学与另外的伴随的喷雾器化学上被分开的喷雾器,用与一个精力DispersiveX光线分光计(SEM-EDX)装备的一台扫描电子显微镜。结果显示大多数BC喷雾器是在直径并且与同类的表面的大约50nm的球形的粒子。结果也证明这些粒子与另外的喷雾器或与自己一起聚集形成更大在测微计范围聚结。这些50-nmBC球形的粒子的形状被发现很类似于免除石油动力的车辆的内燃机的BCparticles的。这些球形的BCparticles被显示与发现帮助usingMatrix的激光解吸附作用/电离蒂米夫莱特·马斯·斯佩克特罗梅特里(MALDI-TOF-MS)的以前报导的fullerenes不同。
简介:IntheprocessofsynthesisofnanometerSiCprecursorswithsol-gelofSiO2andlignin,theproductsofallsizesrequiredcanbecontrolledbytheconcentrationofreac-tants,pH,temperature,ractionandageingtime,andsoon.Thebestconditionsinthisreserchare:theconcentrationofNa2SiO3andorganicmattersare4.50%and26.4%respectively,pH=3.3,T=65℃,ageingtimeis30min,driedat150℃,thesizeofSiCprecursorsisabout2.0μm。
简介:为在水样品的踪迹水银的分析的一个新方法被开发,基于用象由冷蒸汽的稳固的阶段提炼之物和决心的修改dithizone的纳米钛二氧化物(TiO2)的preconcentration/separation的联合原子吸附spectrometry(CVAAS)。Dithizone与酒精被溶解并且在缩放nano的TiO2粉末的表面上装载了由激动人心。修改dithizone的nanoparticles上的Hg2+的静态的吸附行为详细被调查。为Hg2+的优秀吸附比率能与15min,和3.5摩尔的5mL的一摆动时间在78的pH范围被获得,这被发现
简介:TiO2nanoparticleswithdifferentphasesarepreparedbyhydrolysisoftitaniumtetrabutoxideinthepresenceofHCl.ThecompositionandmicrostructureoftheresultingsamplesarestudiedbyXRDandTEM.TheseresultsshowthattherangeofparticlesizeofTiO2isfrom20to30nm.ThemechanismofTiO2photocatalysisreactionhasbeendiscussedextensively.PhotocatalyticactivitiesofnanometerTiO2arealsoevaluatedbydegradationofthecrystalvioletsolution.ExperimentalresultsindicatethatthesynergisticactionofH2O2andultrasonicwavegreatlyenhancesphoto-catalyticreactionofTiO2.