简介：Gasphasereductionofcarbonmonoxidetoformaldehydeandethylenewasfoundinelectrochemicalcellwithaninorganicionexchangerα-Zr(HPO4)2·H2Ousedassolidproton-conductingelectrolyteatroomtemperatureandatmosphericpressure.ThetypeandamountoftheelectroreductionofCOdependonthedifferentmetalelectrodesandcurrentdensities,whichgivesalankbetweenheterogeneouscatalysisandelectrochemistry.
简介：Ionothermalsynthesiswasusedtoprepareanovelaminoacidcontaininghybridzincophosphatemonomer,[Zn(HPO4)(H2PO4)][C6H10N3O2](denotedasZnPO-CJ58).Theinorganicframeworkof[Zn(HPO4)(H2PO4)]·[C6H10N3O2]consistsof4-memberedringsformedbyZnO3OHisandPO2(OH)2tetrahedra.TheHPO4andaminoacidmoietieshangontheZncenter.Suchaframeworkisstabilizedbyextensivemultipointhydrogenbondsinvolvingthephosphateunitsandhistidinemoleculestoformapseudo-3Dsupramolecularstructure.ItisnoteworthythatZnPO-CJ58isthefirstzincphosphateclusterwithaminoacidactingastheligand.Itexhibitsphotoluminescenceexcitedatawavelengthof220nm.Interestingly,ZnPO-CJ58cantransformintoalayeredstructure(C6H10N3O2)Zn2·(HPO4)(PO4)·H2O(ZnPO-CJ36)throughfurtherreactingwithwaterorzincacetatedihydrateinwaterat85℃for1h.Thisworkwillbehelpfulforthesynthesisofcrystallineinorganic-organichybridmaterialswithbiofunctionalmolecules.
简介：利用水热法首次合成了具有两种配位环境Cd原子的新型杂多蓝化合物[NH3（CH2）2NH3]5[Cd（H2O）][CdMo12^vO30（HPO4）6（H2PO4）2]·5H2O．通过元素分析、ICP、TG和X射线单晶衍射确定了其组成，使用IR和EPR进行了结构表征．通过N2吸附脱附测定了比表面积和孔径，为催化研究提供了基础数据．结果表明：该晶体为三斜晶系，P-1，空间群；晶胞参数a=1．2002（2）nm，b=1．4651（3）nm，c=2．1192（4）nm，V=3．5642（12）nm^3，p=83．01（3）°，Z=2，F（000）=2932，R1=0．0300，wR2=0．0716．
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![Hydrothermal Synthesis of a New Zinc Phosphite （CsH7N2）2·[Zn3（<b style='color:red'>HPO</b>3）4] with Intersecting 8- and 12-Ring Channels](/image/thesis2 "Hydrothermal Synthesis of a New Zinc Phosphite （CsH7N2）2·[Zn3（<b style='color:red'>HPO</b>3）4] with Intersecting 8- and 12-Ring Channels")
![Ionothermal Synthesis and Phase Transformation of Organic-inorganic Hybrid Neutral Zincophosphate Cluster [Zn（<b style='color:red'>HPO</b>4）（H2PO4）][C6H（10）N3O2]](/image/thesis3 "Ionothermal Synthesis and Phase Transformation of Organic-inorganic Hybrid Neutral Zincophosphate Cluster [Zn（<b style='color:red'>HPO</b>4）（H2PO4）][C6H（10）N3O2]")
![新型杂多蓝化合物[NH3（CH2）2NH3]5[Cd（H2O）][CdMo12^VO30（<b style='color:red'>HPO</b>4）6（H2PO4）2]·5H2O的合成与晶体结构](/image/thesis4 "新型杂多蓝化合物[NH3（CH2）2NH3]5[Cd（H2O）][CdMo12^VO30（<b style='color:red'>HPO</b>4）6（H2PO4）2]·5H2O的合成与晶体结构")