简介:Inthisstudy,theweldingthermalcyclecurveexhibitedtwotemperaturepeaksinhighheat-inputtwin-wireseparate-poolsubmerged-arcweldingandcoarse-grainedheataffectedzoneexistedintheweldedjoint.Theinclusionsofprimaryweldmetalandcoarse-grainedheataffectedzoneofCe-addedSAWshouldbeAl203,MnO,Si02,TiO,Ce2S3,CeS,Ce202SandCe203.Undertheeffectofweldingthermalcycle,oxy-sulfidesinclusionsofCe,thediameterofwhichwaslessthan2.0|Jim,slightlygrewlarger,butthecompositionandtypeoftheinclusionsdidn,tchange.ThemicrostructureofthelargeheatinputweldmetalhadacicularferritethatCeoxidesulphideparticlesinducednucleationandproeutectoidferrite.Inthecoarse-grainedheataffectedzoneofweldmetal,home-positionprecipitationofacicularferriteandsympatheticacicularferritewerebothobserved.Itwassupposedthatpreviouscrystalcellsofacicularferriteinaustenitegrainpromotedhome-positionprecipitationofacicularferrite.Meanwhile,sympatheticacicularferritetendedtonucleateattheprimaryacicularferritegrainboundaries,wherehighdislocationdensitywaslocated,andgrewinsidetheneighboringcarbon-depletedausteniticregions.Thegranularbainitenucleatedintheausteniticzonewithhighcarboncontentclosetoacicularferriteandsympatheticacicularferrite.
简介:MonophasicCe~(3+)andPr~(3+)co-dopedyttriumaluminumgarnet(YAG:Ce~(3+),Pr~(3+))nanoparticleswithgooddispersityanduniformgrainsizesintherangeof50–80nmwerepreparedbyatwo-steproute,whichconsistedofamodifiedco-precipitationpreparationofmixedmetalhydroxidehydrateintermediatesatlowtemperatureofabout40oCandasubsequentcalcinationconversionofthesynthesizedintermediatestocrystallinenanoparticleproductsatabout1000oC.Theinfluencesofboththelanthanideion(Ce~(3+)andPr~(3+))dopingconcentrationanddifferentdoping(Ce~(3+)/Pr~(3+))ratioonthephotoluminescenceintensityweresystematicallyinvestigated.Thesynthesized(Ce_(0.6)Pr_(0.4))_(0.04)Y_(2.96)Al_5O_(12)nanoparticleswerenearsphericalnanoclusterswithgooddispersityanduniformsizesintherangeof50–80nmforabout85%oftheparticles.Thestrongestphotoluminescenceintensitywasobservedforthe(Ce_(0.6)Pr_(0.4))_(0.04)Y_(2.96)Al_5O_(12)nanoparticleproducts.
简介:使用[β-B-BiW9O(33)](9-)作为基本建筑单元,成功合成了多酸做配体的双核Ce(Ⅳ)配合物(Na6H(10){Ce(H2O)3(μ2-OH)[Bi2W(21)O(70)(OH)3]}2·40H2O),通过元素分析、X-射线单晶衍射、XRD、IR和TG表征技术确定了其组成和结构.两核Ce(Ⅳ)离子配合物是通过2个μ2-OH-连接构成的,每个Ce(Ⅳ)离子除了与2个μ2-OH-配位外,还与3个H2O以及[Bi2W(21)O(70)(OH)3](11-)中4个缺位O原子配位,形成三帽三棱柱.[Bi2W(21)O(70)(OH)3](11-)多酸阴离子是通过3个W(Ⅵ)连接形成新的多酸阴离子物种,在缺位结构上留有一个空位恰好与Ce(Ⅳ)离子配位.通过对配合物的电化学分析发现,与硝酸铈铵对比,配合物中Ce(Ⅳ/Ⅲ)的阳极峰电势由0.857减小至0.772V,表明多酸阴离子配体有稳定Ce(Ⅳ)的作用.