简介:Thesupportγ-Al2O3wastreatedwith1-methylnaphthaleneasthemodelreactantbyrespectivelyusingthechemicalstaticadsorptionmethodandtheacceleratedcokingmethodtostudythecokingsitesofγ-Al2O3surface.Thecarbonspeciesformedonγ-Al2O3surfacewereanalyzedbyCAT-CS,TG-MS,IR-OH,andPy-IRtechniques.TheresultsofcharacterizationbyCAT-CSandTG-MStechniquesindicatedthatthecarbonspeciesformedduringthechemicalstaticadsorptionprocessismainlycomposedofthereversiblyadsorbedcokeprecursorswithalowly-condensedstate,whilethatformedaftertheacceleratedcokingprocessisprobablyrelatedwiththeirreversiblyadsorbedcokedepositswithahighly-condensedstate.TheresultsofcharacterizationbyIR-OHandPy-IRtechniquesfurtherimpliedthattheformationofthetwokindsofcarbonspecies,i.e.,cokeprecursorsandcokedeposits,arecloselyrelatedwiththebasichydroxylgroupsandthestrongLewisacidsitesonγ-Al2O3surface.Theresultsleadtoadeepinsightintothecokingmechanismonthealuminasurface.
简介:Compositematerials(AZ-x)werepreparedbymixingthenanosizedHYzeoliteandγ-Al2O3usingthesol-gelmixingmethodandwereemployedasthesupportforNiMocatalysts(NiMo/AZ-x).ThesecompositesandcatalystswerecharacterizedbyXRD,BET,TPD,TPR,HRTEMandFT-IRspectroscopy.ComparedwiththeNiMocatalystsupportedonγ-Al2O3(NiMo/γ-Al2O3),theseNiMo/AZ-xcatalystsshowhigheractivityinthehydrodesulfurization(HDS)ofFCCdiesel,andtheHDSactivityincreaseswithanincreasingHYmasscontentinthecomposites,providedthattheHYmassfractiondoesnotexceed20%.Comparedwithγ-Al2O3,theintroductionofnanosizedHYzeolitecanimprovetheporousstructureofthecomposites,whichcanbenefitthemasstransferofthereactantmolecules.Furthermore,thenanosizedHYzeoliteinthecompositescanmodifytheirsurfacepropertieswhichwouldincreasetheratioofmetalspeciestobetransformedintoreduciblephaseinlowtemperatureregionandmodifythemorphologyoftheMoS2phasestoformmoremulti-stackedMoS2activephaseswithincreaseddispersionofedgesandcornersofMoatoms.