简介:TheesterificationoflauricacidwithmethanolcouldbeefficientlycatalyzedbyZrOCl2·8H2O,andthisreactionwasstudiedtodevelopagreenmethodforbiodieselproduction.Theinfluencingfactors,suchasamountofcatalyst,reactiontimeandmolarratioofacidtomethanol,wereinvestigated.TheresultsindicatedthattheZrOCl2·8H2Ocatalystshowedhighcatalyticactivity,andgavea97.0%methyllaurateconversionrateunderthefollowingoptimizedconditions,viz.:alauricacid/methanolmolarratioof1:10,acatalystdosageof4%,andareactiondurationof2hatmethanolrefluxingtemperature.Thecatalystcouldbeeasilyrecoveredwhileitsactivitycouldbewellretainedafterthreecycles.TheZrOCl2·8H2Ocatalystalsoexhibitedexcellentcatalyticactivityfortheesterificationofdifferentfreelong-chainfattyacids(includingnonedibleoilswithhighacidvalue)withdifferentshortcarbonchainalcohols.Therefore,theZrOCl2·8H2Ocatalysthasgoodpotentialforthesynthesisofbiodieselfromlow-costfeedstockssuchaswastevegetableoilsandnon-edibleoils.
简介:Throughimprovingtheagingprocessduringsynthesisofthesupport,γ-Al2O3withlargeporevolumeandhighsurfaceareawassynthesizedbyafacilesecondaryreformingmethod.Thesynthesisparameters,suchasthereactiontemperature,thefirstagingtemperatureandthesecondagingtemperature,wereinvestigated.Thetexturalpropertiesofγ-Al2O3werecharacterizedbymeansofN2adsorption-desorptionisotherms,X-raypowderdiffractometry(XRD),scanningelectronmicroscopy(SEM),Fouriertransforminfrared(FTIR)spectroscopyandthermogravimetry(TG).TheexperimentalresultsindicatedthatAACHandamorphousAlOOHweretheprecursorsofalumina,whichwereformedviaprecipitationfromsolutionsafterreactionofaluminumsulphatewithammoniumhydrogencarbonate.Theprecursornanocrystallitesgrewandre-assembledduringthesecondaryreformingprocess,whichresultedinanincreasedporesizeandporevolumeandadecreasedbulkdensity.Theas-synthesizedγ-Al2O3materialsfeaturedmeso/macroporosity,largeporevolume(2.175cm3/g),highsurfacearea(237.8m2/g),andlowbulkdensity(0.284g/mL).
简介:据岩心、铸体薄片、扫描电镜和常规物性等资料,结合测井解释成果,对鄂尔多斯盆地镇原地区长8油层组砂岩储层特征进行了研究。结果表明:长8油层组砂岩储层曾遭受酸性介质的改造,次生孔隙发育:储集空间以剩余原生粒间孔、粒问溶孔和微裂缝为主,黏土矿物晶间微孔对储层物性也有贡献;储层发育受沉积相、碎屑组分、成岩和构造作用共同影响,其中沉积微相影响储层的空间展布;碎屑组分和粒度与储层物性具有直接关系:成岩作用对储层物性的影响有利有弊,压实和胶结作用可使原生孔隙大部分丧失.而溶蚀作用形成的次生孔隙可大幅度提高储层的孔、渗性,为形成优质储层的关键。
简介:延长组长8油层组是鄂尔多斯盆地镇原地区重要的储集层之一。通过岩心观察以及测井和分析测试资料的研究.结合前人研究成果,对长8油层组进行了精细的沉积相分析,确定长8油层纽属于辫状河浅水三角洲沉积体系。并从中识别出主河道、分流河道、决口扇、水下分流河道、分流间湾、分流间洼地、河口坝及远砂坝等沉积微相。在精细高分辨率层序地层分析和建立等时地层格架的基础上,以相当于小层砂体的短期旋回层序为等时地层单元编制层序一岩相古地理图,并分析各类成因砂体的发育、组合和演化特征及展布规律。研究结果可为该区长8油层组的储层预测和岩性油藏的高效勘探开发提供精细的沉积、层序资料。
简介:TheMoS2catalystswerepreparedfromvariousmolybdateprecursorsincludinginorganicandorganicmolybdatecompounds.ThesulfidationdegreeandmorphologyofactivephasesofMoS2activatedbyvariousmolybdateprecursorsinH2S/H2streamatdifferenttemperatureswerestudiedbyX-rayphotoelectronspectroscopy(XPS)andhigh-resolutiontransmissionelectronmicroscopy(HRTEM).TheorganicmolybdateprecursorsleadtoMoS2catalystswithhighersulfidationdegreeandsmalleractivephasestodemonstratehighercatalyticactivityduringhydrodesulfurizaiton(HDS)of4,6-DMDBT.
简介:Inthispaper,2-isopropylnaphthalenehasbeensynthesizedbythereactionofnaphthaleneandisopropylbromide,usingtriethylaminehydrochloride-aluminumchlorideionicliquidasthecatalyst.Theeffectofthecatalystcomposition,thereactiontime,thereactiontemperature,theionicliquiddosage,aswellasthemolarratioofthereagentsonthe2-isopropylnaphthaleneyieldwassystematicallyinvestigated.Theoptimalreactionconditionscover:anAlCl3toEt3NHClratioof2.0,areactiontimeof3h,areactiontemperatureof15.0℃,avolumefractionofionicliquidtothemixture(isopropylbromide,n-dodecaneandn-hexane)of9%,andanaphthalene/isopropylbromidemolarratioof4.0.Undertheoptimalreactionconditions,theconversionofisopropylbromidereached98%andtheselectivityof2-isopropylnaphthalenewasequalto80%.ThetestresultsverifiedgoodcatalyticactivityuponusingEt3NHCl-AlCl3ionicliquidasthecatalystforalkylationofnaphthalenewithisopropylbromide.Theactivityoftheionicliquidremainsunchangedafterithasbeenrecycledfor4times.
简介:鄂尔多斯盆地西仁沟地区延长组长2储层为典型的低渗储层。针对其形成因素复杂、分布规律认识不清等问题,采取微观观察与宏观钻井统计相结合的方法,在大量铸体薄片、扫描电镜、物性及钻井等资料分析的基础上,对该区长2储层砂岩的沉积特征、岩石学特征、孔渗特征、成岩作用类型、孔隙类型及孔隙结构等进行了深入研究。结果表明:形成于分流河道沉积背景下的长2储层砂岩具有沉积物粒度偏细、成熟度较低的岩石学特征,储集空间主要为原生粒间孔隙和次生溶蚀孔隙.圈闭类型主要为构造一岩性圈闭;大量发育的泥质和钙质夹层造成油水纵向分异程度较差,并进一步分隔油层,使单油层层内非均质性增强。总体上西仁沟地区长2储层的宏观展布受局部构造、储层岩性和物性的综合控制,对优质储层的展布具有重要的影响。