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  • 简介:LigandeffectofthecatalyticsystemWCl6-Et2AlClforringopeningmetathesispolymerization(ROMP)ofdicyclopentadiene(DCPD)wasinvestigated.Theexperimentalresultsshowthataddingstericallyhinderedphenol-2.6-di-tert-butylcresylol(DTBC)inthecatalyticsystemnotonlycanobviouslyincreasethemonomerconversionofpolymerizationbutalsoimprovethemechanicalproperties,suchasnotchedimpactstrength(NIS),tensilestrength(TS)ect.,ofthesynthesizedpolydicyclopentadiene(PDCPD),Asimilareffectcanbeobservedbyusingastericallyhinderdpolymericphenol-linearphenolformaldehyderesin(LPF)asaligand.

  • 标签: 二聚环戊二烯 聚合过程 催化系统 配位效应