简介:TheA-Bblockcopolymerof0634-chloroethylglycidyletherwithstyrenecanbegotbytheeasymethodofone-steppolymerization.ThestructureofA-Bblockcopolymerwasconfirmedbytheelementaryanalysis,turbiditytitration,molecularweightmeasurement,IR-spectra,13C-NMR,1H-NMRandDTAinvestigationoftheproducts.Also,theeffectsofsolvents,reactiontimeandtemperatureonthecomposition,Mnandyieldofcopolymerhavebeenstudied.
简介:Averymildandextremelyefficienthydrolysismethodfortransformationofpolystyrene-b-poly(tert-butylacrylate)(PS-b-PtBA)topolystyrene-b-poly(acrylicacid)(PS-b-PAA)wasdesignedandcarriedoutusingmoreconvenientandinexpensivechlorotrimethylsilane/sodiumiodideasreagents.Thehydrolysisproductcanself-assembleinaqueousmediatogiveregularmicelleswithPSblockformingthecoreandPAL4blockformingthecorona,orintetrahydrofuran(THF)togivereversemicelleswiththehydrophilicblockinthecore.
简介:Inthiswork,DSCandSEMstudiesindicatethation-ligandinteractioncanbeutilizedtoenhancetheinteractionofpoly(styrene-block-2-vinylpyridine)[P(S-b-2VP)]andpolyethylenebasedionomer(Surlyn).Thecompatibilityforthisblendingsystemcanbeimprovedbythisspecialinteractionand20/80wtistheoptimumblendingcompositionwithgoodcompatibility.FTIRresultsfurthercertifythatstronginteractionsexistintheblendingsystem.
简介:Thediblockcopolymersintercalatedlayeredsilicatewaspreparedviaameltdispersiontechnique.Thentheeffectofintercalatedhybridasfilleronacrylonitrile-butadiene-styreneresinwascharacterizedbyX-raydiffraction,transmissionelectronmicroscopy,stress-strainmeasurementsinelongation.