学科分类
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7 个结果
  • 简介:Optimizationofcompositionandmicrostructureisimportanttoenhanceperformanceofsolidoxidefuelcells(SOFC)andlithium-ionbatteries(LIB).Forthis,theporouselectrodestructuresofbothSOFCandLIBaremodeledasabinarymixtureofelectronicandionicconductingparticlestoestimateefectivetransportproperties.Particlepackingsof10000spherical,binarysizedandrandomlypositionedparticlesarecreatednumericallyanddensifiedconsideringthediferentmanufacturingprocessesinSOFCandLIB:thesinteringofSOFCelectrodesisapproximatedgeometrically,whereasthecalenderingprocessandvolumechangeduetointercalationinLIBaremodeledphysicallybyadiscreteelementapproach.Acombinationofatrackingalgorithmandaresistornetworkapproachisdevelopedtopredicttheconnectivityandefectiveconductivityforthevariousdensifiedstructures.ForSOFC,asystematicstudyoftheinfluenceofmorphologyonconnectivityandconductivityisperformedonalargenumberofassemblieswithdiferentcompositionsandparticlesizeratiosbetween1and10.Incomparisontopercolationtheory,anenlargedpercolationareaisfound,especiallyforlargesizeratios.Itisshownthatincontrasttoformerstudiesthepercolationthresholdcorrelatestovaryingcoordinationnumbers.Theefectiveconductivityshowsnotonlyanincreasewithvolumefractionasexpectedbutalsowithsizeratio.ForLIB,ageneralincreaseofconductivityduringtheintercalationprocesswasobservedincorrelationwithincreasingcontactforces.Thepositiveinfluenceofcalenderingonthepercolationthresholdandtheefectiveconductivityofcarbonblackisshown.Theanisotropycausedbythecalenderingprocessdoesnotinfluencethecarbonblackphase.

  • 标签: 有效电导率 电极结构 细观力学模型 固体氧化物燃料电池 锂离子电池 粒状
  • 简介:Consideringtheefectsofosmoticpressure,elasticbending,Maxwellpressure,surfacetension,aswellasfexo-electricanddielectricpropertiesofphospholipidmembrane,theshapeequationforspherevesicleinalternation(AC)electricfeldisderivedbasedontheliquidcrystalmodelbyminimizingthefreeenergyduetocoupledmechanicalandACelectricalfelds.Besidestheefectofelasticbending,theinfuenceofosmoticpressureandsurfacetensiononthefrequencydependentbehaviorofvesiclemembraneinACelectricfeldisalsodiscussed.Ourtheoreticalresultsformembranedeformationareconsistentwithcorrespondingexperiments.Thepresentmodelprovidesthepossibilitytofurtherdisclosethefrequency-dependedbehaviorofbiologicalcellsinthecoupledACelectricanddiferentmechanicalfelds.

  • 标签: 交流电场 变形模型 液晶 弹性弯曲 表面张力 磷脂膜
  • 简介:Cementationisproducedbymixingacertainamountofcementwiththesaturatedclay.Thepurposeofthispaperistomodelthecementationeffectonthemechanicalbehaviorofcement-treatedclay.Amicromechanicalstress-strainmodelisdevelopedconsideringexplicitlythecementationatinter-clustercontacts.Theinter-clusterbondinganddebondingduringmechanicalloadingareintroducedintwoways:anadditionalcohesionintheshearslidingandahigheryieldstressinnormalcompression.Themodelisusedtosimulateisotropiccompressionandundrainedtriaxialtestsundervariousconfiningstressesoncement-treatedSingaporeclaywithvariouscementcontents.Theapplicabilityofthepresentmodelisevaluatedthroughcomparisonsbetweennumericalandexperimentalresults.Theevolutionoflocalstressesandlocalstrainsininter-clusterplanesisdiscussedinordertoexplaintheinducedanisotropyduetodebondingatcontactlevelundertheappliedloads.

  • 标签: 水泥含量 土模型 不排水三轴试验 细观 饱和粘土 屈服应力
  • 简介:Liquidsolid使流体化床在处理工业基于粒子尺寸,密度,和形状分开粒子的矿物质被使用。理解扩展的使流体化的床为精确地估计它的表演是重要的。使流体化的床的扩大特征被与铁矿石,铬铁矿,石英,和煤样品执行几个实验学习。把水用作液体媒介,实验被进行在使流体化的床上学习粒子尺寸,粒子密度,和表面的速度的效果扩大。试验性的数据被利用基于维的分析开发一个实验数学模型以粒子特征估计使流体化的床的扩大比率,操作并且设计参数。从数学模型获得的预言的扩大比率在对试验性的数据的好同意。

  • 标签: 数学模型 流化床 膨胀率 粒子间相互作用 颗粒密度 实验数据
  • 简介:Stent-graftimplantationisanimportantmeansofclinicaltreatmentforaorticdissectinganeurysm(ADA).However,researchesonfluiddynamicseffectsofstentwererare.ComputersimulationwasusedtoinvestigatetheinteractionsbetweenbloodstreamandvascularstructureinastentedADA,whichendurestheperiodicpulsevelocityandpressure.Weobtainedandanalyzedtheflowvelocitydistribution,thewalldisplacementandwallstressintheADA.Bycomparingthedifferentresultsbetweenanon-stentedandastentedADA,wefoundthattheinsertionofavasculargraftcanmakethelocationofmaximumstressanddisplacementmovefromtheaneurysmlumenwalltothearterywall,accompaniedwithagreatlydecreaseinvalue.Theseresultsimplythattheplacementofastent-graftofanykindtooc-cludeADAwillresultinadecreasedchanceofrupture.

  • 标签: 相互作用 动脉瘤 管结构 主动脉 数值研究 夹层
  • 简介:Analternateyetgeneralformoftheclassicaleffectivethermalconductivitymodel(Maxwellmodel)fortwo-phaseporousmaterialsispresented,servinganexplicitthermo-physicalbasis.Itisdemonstratedthatthereducedeffectivethermalconductivityoftheporousmediaduetonon-conductingporeinclusionsiscausedbythemechanismofthermalstretching,whichisacombinationofreducedeffectiveheatflowareaandelongatedheattransferdistance(thermaltortuosity).

  • 标签: Maxwell模型 两相多孔介质 物理基础 热拉伸 有效导热系数 一般形式