简介：Phosphorus(P)fractionationandsorptionbehaviorwerestudiedinthesedimentsoftwocalcium-sulfate(Ca-SO4:Ca2t170mgL-1;SO42-400mgL-1)waterreservoirsinthesoutherncentralArgentineAndes-ElCarrizalReservoir(ECR),whichstratifiesinsummerandElNihuilReservoir(ENR),whichisverticallymixedthroughouttheyear.Sedimentsizeclassesreflectedthelithologyofbothbasinsandthereservoirsrelativelocation:ECR(downstreamfromavalleyadjacenttoamountainenvironment)hadhigherclayproportionswhilethesandfractionwasmoreimportantinENR(justnexttoamountainenvironment).Inbothreservoirs,thechemicalcompositionrevealedlowalterationandcalciumenrichment.TotalPcontentwasrelativelyhigh(1.1-1.6mgPkg-1dryweight)asexpectedfromthecontributionofmarineformations.PfractionationwasdominatedbyCa-P(ECR,69%andENR,63%)followedbyorganic-P(23%)insummer-anoxicECRandbyiron/aluminum(Fe/Al)-P(27%)inoxicENR.BatchexperimentsshowedthatsorptionbehaviorinECRhadatypicalLangmuirisothermplotwhileinENRthatmodelfittedonlyatlowdissolvedPvalues(o5mgPL-1)andco-precipitationevidencewasobservedathigherPconcentrations.ItisproposedthatlowerFe/Al-Pcontentinanoxic(ECR)vs.oxic(ENR)sedimentsresultsfromthePreleasedfromiron-boundphosphorusduetosulfatereduction-ferroussulfideformationinananoxicenvironment.ThisconditionshouldenableECRsedimentstoadsorbPintofreshoxidizediron,andENRsedimentstoco-precipitatePwithcalciumduetoFe/Al-Psaturation,asobservedinbatchexperiments.ThispaperconstitutesthefirstdescriptionofphosphoruscontentanddynamicsinreservoirsedimentsinaridcentralwesternArgentina,wherewatersulfateconcentrationsarenaturallyhighduetobasinlithology.

简介：为了有效处理人工源的影响,本文开发了带源的CSAMT二维正反演算法,可用于全区（近区、过渡区和远区）资料的反演。引入正则化因子完成磁法二维反演,并且将模型参数调整为磁化率的对数,保证反演过程中磁化率始终为正值。本文基于交叉梯度原理,将CSAMT和磁法进行联合反演,通过搜索交叉梯度项权重的方法,避免了不同异常源引起的两种异常相互干扰的问题。理论模型算例表明基于交叉梯度的联合反演方法优于单独反演。本文开发的带源CSAMT二维正反演算法,有效处理了人工源的影响,保证了最终联合反演算法的可靠性。