Synthesis, Characterization of Heterodinuclear Co-Cu Complex and Its Electrocatalytic Activity towards 02 Reduction： Implications for Cytochrome c Oxidase Active Site Modeling-中国期刊网

摘要 Anewdinudeatingligandconsistingofatetraphanylporphyrinderivativecovalentlylinkedwithtris(2-benzimidazylmethyl)-amineanditshomodinudearCo-CoandheterodinnelearCo-Cucomplexesweresynthesizedandspectroscopicallycharacter-ized.Theheterobimetalliecobalt-coppercomplexbearingthreebenzimidazoleligandsforcopper,ascytochromecoxidaseac-tivesitemodel,wasappliedtothesurfaceofglassycarbonelec-trodetoshowelectrocatalytieactivityforO2reductioninaque-oussolutionatanaddityleveldosetophysiologicalpHvalue.Thekineticparametersofthiselectrocatalyticprocesswereob-tained.

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Synthesis, Characterization of Heterodinuclear Co-Cu Complex and Its Electrocatalytic Activity towards 02 Reduction： Implications for Cytochrome c Oxidase Active Site Modeling

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Synthesis, Characterization of Heterodinuclear Co-Cu Complex and Its Electrocatalytic Activity towards 02 Reduction： Implications for Cytochrome c Oxidase Active Site Modeling

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