Electrochemical reduction process of bilirubin in dimethylformamide-中国期刊网

摘要 Theelectrochemicalreductionbehaviorofbilirubin(BR)atplatinumelectrodeinDMFwasinvestigatedbycyclicvoltammetry,insituelectronspinresonancespectroscopyandinsiturapidscanningthinlayerspectroelectrochemistry.ExperimentalresultsrevealedthatthereductionofBRfirstlyundergoesanECEprocess:BR-+eBR-dimerize(BR)22-+e(BR)23-.Thegenerated(BR)23-canbere-oxidizedtoBRandthentopurpurin(Pu)byaseriesofoxidationprocesses:(BR)23--e(BR)22--2e2BR,BR--2eBV--2ePu.However,there-reductionreactionsofPuarenotthereverseprocesses.Thedifferentreductionmechanismsarediscussedindetail.

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Electrochemical reduction process of bilirubin in dimethylformamide

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Electrochemical reduction process of bilirubin in dimethylformamide

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