摘要
Severalkindsofnovelazobenzene-containingpolyelectrolyteswithspecialmoleculardesignhavebeendevelopedfromacryloylchlorideorepoxybasedprecursorpolymers.Theacryloylchloridebasedprecursorpolymer,poly(acryloylchloride),waspreparedbyfreeradicalpolymerizationofacryloylchloride.Theazopolyelectrolyteswerepreparedbyanesterificationreactionbetweentheprecursorpolymerandcorrespondingazochromophorescontainingareactivehydroxylgroup,followedbyhydrolysisoftheunreactedacylchloridegroups.Theepoxybasedprecursorpolymerwaspreparedbythereactionbetween1,4-cyclohexanedimethanoldiglycidyletherandaniline,andpostfunctionalizedbyazocouplingreactiontoformazopolymerscontainingchromophoreswithionizablegroups.Thepolyelectrolyteswerecharacterizedbyelementalanalysis,~1H-NMR,IRandUV-Visspectroscopy.Thephotodynamicandphotoresponsiveproperties,aswellasself-assemblyoftheseazopolyelectrolytesarereportedinthispaperp.
出版日期
2000年04月14日（中国期刊网平台首次上网日期，不代表论文的发表时间）
