THE EFFECT OF CLAY DISPERSION ON THE CRYSTALLIZATION AND MORPHOLOGY OF POLYPROPYLENE／CLAY COMPOSITES-中国期刊网

摘要 PP/claycompositeswithdifferentdispersions,namely,exfoliateddispersion,intercalateddispersionandagglomeratesandpanicle-likedispersion,werepreparedbydirectmeltintercalationorcompounding.TheeffectofclaydispersiononthecrystallizationandmorphologyofPPwasinvestigatedviaPLM,SAXSandDSC.Experimentalresultsshowthatexfoliatedclaylayersaremuchmoreefficientthanintercalatedclayandagglomeratesofclayinservingasnucleationagentduetothenano-scaledispersionofclay,resultinginadramaticdecreaseincrystalsize(lamellarthicknessandspherulites)andanincreaseofcrystallizationtemperatureandcrystallizationrate.Ontheotherhand,adecreaseofmeltingtemperatureandcrystallinitywasalsoobservedinPP/claycompositeswithexfoliateddispersion,duetothestronginteractionbetweenPPandclay.Comparedwithexfoliatedclaylayers,theintercalatedclaylayershavealessimportanteffectonthecrystallizationandcrystalmorphology.Noeffectisseenforsampleswithagglomeratesandpanicle-likedispersion,inregardtomeltingtemperature,crystallizationtemperature,crystalthicknessandcrystallinity.

1S. Aslanzadeh R. Semnani Rahbar M. Nazi. Accelerating Role of Clay in Photo-Oxidation of Polypropylene/Clay Multifilament Yarns.高分子化学,2014-05.
2Li-mei Wang;Ai-hua He. PREPARATION OF POLYPROPYLENE/CLAY NANOCOMPOSITES BY in situ POLYMERIZATION WITH TiCl4/MgCl2/CLAY COMPOUND CATALYST.高分子化学,2011-05.
3. Magic Clay.教育学,2014-04.
4. Effect of Wood Variables on the Properties of Wood Fiber-Polypropylene Composites.林学,2002-04.
5Jing-bin Chen;Jia-zhuang Xu;Huan Xu;Zhong-ming Li;钟淦基;雷军. The Crystallization Behavior of Biodegradable Poly（butylene succinate） in the Presence of Organically Modified Clay with a Wide Range of Loadings.高分子化学,2015-04.
6. Effect of Wood Particle Size on the Properties of Wood/Polypropylene Composites Ⅰ:Mechanical Properties.林学,2002-01.
7ZHANG Wei;ZHANG Fawang;HAN Zhantao;Lü Xiaoli;LIN Daohui;David WERNER. Effect of Clay Minerals on Transport of Surfactants Dispersed Multiwalled Carbon Nanotubes in Porous Media.地质学,2017-01.
8. A World of Clay Architecture In Ngari.历史学,1996-04.
9. Folk Art： Clay Figurines （Part Ⅱ）.中外政治制度,2008-09.
10LIJia－ju;HOULei;等. Synthesis of β‘—SIALON Powder from Clay.硅酸盐工业,1995-04.

THE EFFECT OF CLAY DISPERSION ON THE CRYSTALLIZATION AND MORPHOLOGY OF POLYPROPYLENE／CLAY COMPOSITES

来源期刊

相关推荐

同分类资源更多

相关关键词

THE EFFECT OF CLAY DISPERSION ON THE CRYSTALLIZATION AND MORPHOLOGY OF POLYPROPYLENE／CLAY COMPOSITES

来源期刊

相关推荐

同分类资源 更多

相关关键词

同分类资源更多