CHARACTERIZATION OF NOVEL POLYMERIC INTERMEDIATE POLY(p-BROMOACETYL STYRENE) CROSSLINKED BY DIVINYLBEZENE

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摘要 Acetylcrosslinkedpolystyrene(EPS)andcrosslinkedbromoacetylpolystyrene(BEPS)beadsweresynthesizedbyFridel-Craftsacetylationofpolystyrene(PS)andbrominationofEPSrespectively.FTIR,XPS,andTG-TDGwereemployedtocharacterizetheirstructures.TheresultsrevealedtherearetwotypesofbromineintheBEPSmolecule.Oneisinthemainchainofpolystyreneandtheotherisintheacetyl.TheresultsofTG-DTGshowedthattheratesoflossweightofPS,EPS,andBEPSwere92.7%,92.2%,and81.3%amongthe300℃~500℃;7.3%,7.8%,and18.7%in594℃,660℃,and584.8℃,respectively.
机构地区 不详
出版日期 2003年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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