学科分类
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29 个结果
  • 简介:氨氧化在海洋的沉积在氮周期起一个重要作用。氧化氨的archaea(AOA)和betaproteobacteria的季节、空间的分发(在来自华东海(ECS)的表面沉积的-AOB)用氨monooxygenase子单元(amoA)被调查基因。为了描绘AOA和-AOB,的社区,即时量的聚合酶链反应(qPCR)在这研究被执行,与环境参数一起。许多-AOBamoA基因(cDNA的快速的扩大结束的2.17d(种族)联系了基因获得三热压力回答的全身的序列:(1)热吃惊蛋白质70(OvHSP70),(2)热吃惊抄写因素(OvHSF),并且(3)O的热吃惊因素绑定蛋白质(OvHSBP)。vulgaris。OvHSP70,OvHSF,和OvHSBP蛋白质包含了2222bp,2264bp,分别地为635,458和90氨基酸编码了的841bp。多重顺序排列的结果证明OvHSP70的氨基酸序列高度关于另外的种类被保存。同样,謔?謔??

  • 标签: 表层沉积物 空间分布 氨氧化 微生物群落 季节 AMOA基因
  • 简介:Studyonoxidizingcelluloseto2,3-dialdehydecellulosebysodiumperiodate(NaIO4)wascarriedout.TheeffectsofreactionconditionssuchaspHofsolution,temperature,oxidantconcentration,oxidationtime,theparticlesizeof2,3-dialdehydecelluloseandalkalitreatmenttemperatureonthedialdehydeconcentrationofcellulosewereinvestigatedindetail.Theresultsshowthatthealdehydegroupcontentwascreatedwhilereactiontemperatureandalkalitreatmenttemperatureincreased.Themostprincipalfactorsaffectingthealdehydegroupcontentof2,3-dialdehydecellulosewerefoundoutandthebestoxidationconditionswereasfollows:thepHwas2,thereactiontemperaturewas45℃,themassratioofcellulosetoNaIO4was1/2,thereactiontimewas4h,thealkalitreatmenttemperaturewas70℃andsmallerparticlesizewas0.80mm.

  • 标签: 氧化纤维素 二醛纤维素 高碘酸盐 化学分析
  • 简介:TheunimolccularreactionsofammoniaoxideH3NO,isomerizationanddehydrogenation,areinvestigatedbyabinitioMOcalculationswiththe4-31Gbasisset.Thegeometriesandenergiesofthereactant,transitionstatesandproductshavebeendeterminedonthesingletpotentialenergysur-face.Thereactionergodographyalongtheintrinsicreactioncoordinate(IRC)forthetworeactionshavebeenperformed.ThevibrationalfrequencycorrelationdiagramofthetworeactionsareanalyzedalongtheIRC.

  • 标签: AMMONIA VIBRATIONAL reactant intrinsic SINGLET Andrews
  • 简介:有效的氨兆兆赫(THz)洞激光试验性地被报导。不同于象洞couplers和独立网孔couplers那样的过去的设计计划,在我们的系统,输入和输出couplers被扔镍制作ZnSe和高抵抗力的硅底层上的电容的金属性的网孔。因此couplers能不仅作为一个F-P振荡器被构造而且能是封上更容易执行排列的调整与的窗户被使用。为了提高THz激光,输出精力和光子变换效率,象泵紧张那样的主导的因素和煤气的压力试验性地被调查。最后,有在1.09kPa操作的90m波长(3.33THz)的氨激光的1.35mJ兆兆赫放射与9R(16)由402mJ茶CO2激光抽了线被产生,并且6.5%的光子变换效率被完成。

  • 标签: 太赫兹辐射 转换效率 激光器 光子 金属网格
  • 简介:Theexperimentalandnumericalinvestigationsoftheflowwithreactionoftwogases:hydrogenchlorideHClandammoniaNH3wereperformed.ThearticlecontainsdescriptionofthevisualisationmethodoftheformationandflowofparticlesofammoniachlorideNH4Cl.Analysesofmeanconcentrationandvarianceofconcentrationfluctuationsofdispersedphasewereperformedfordifferentoutputsofgases.Numericalcalculationswereperformedforanalysedphenomenon.Bothnumericalandvisualisationresutswerematchedandcompared.

  • 标签: HCL NH3 氯化氢 氨气 混合气体 紊流
  • 简介:研究地西泮、苯巴比妥、普萘洛尔和西咪替丁对地西泮氧化代谢的影响及其药酶蛋白的初步分析,应用HPLC,SDS聚丙烯酰胺凝胶电泳和薄层扫描测定地西泮及其代谢物,并对大鼠肝微粒体和酶蛋白进行分离和含量测定。结果表明地西泮、普萘洛尔和西咪替丁使肝微粒体中P450含量明显降低。地西泮和普萘洛尔明显抑制地西泮C3羟化活性,大剂量普萘洛尔尚能抑制地西泮N脱甲基。苯巴比妥明显诱导P450生成,增强地西泮N脱甲基和C3羟化酶活性及分子量为51,000和59,000的电泳蛋白带,而地西泮、普萘洛尔则呈抑制作用。并发现,地西泮N脱甲基酶活性和分子量为59,000蛋白含量呈线性相关(P<0.05),而C3羟化酶活性则与51,000蛋白含量呈线性相关(P<0.01)。因此地西泮C3羟化代谢可能与51,000的P450酶蛋白有关,而N脱甲基代谢则可能与59,000的P450酶蛋白有关。

  • 标签: 地西泮 去甲西泮 替马西泮 药酶诱导剂 药酶抑制剂 N-脱甲基化酶
  • 简介:Thesurfaceofpolypropylene(PP)membranewasmodifiedbylowtemperatureplasmawithammonia.Theeffectofexposuretimewasinvestigatedbymeansofcontactanglemeasurement.Theresultsshowthatlowtemperatureammoniaplcsmatreatmentcanenhanceitshydrophilicity.Chinesehamsterovary(CHO)cellsattachmentonthemodifiedmembranewasenhancedandthegrowthrateonthemembranewasfasterthanunmodifiedone.

  • 标签: 聚丙烯 等离子体 CHO细胞 实验
  • 简介:NH^+4-N对吴郭鱼的24小时半致死浓度为41.39ppm,当水中NO^2--N浓度维持在6.4ppm时,对吴郭鱼24小时半致死浓度为44.58ppm。48小时半致死浓度为41.55ppm.当PH9.6时,对鲤鱼的24小时半致死浓度为6.02ppm,当PH为8.9时为8.57ppm,当PH8.2时为18.45ppm,PH8.0时为22.31ppm,PH7.S时为48.18ppm,PH7.0时则超过100ppm。

  • 标签: 吴郭鱼 半致死浓度 鲤鱼 PH 毒性试验 维持
  • 简介:Theetchingeffectofammonia(NH3)onthegrowthofverticallyalignednanotubes/nanofibers(CNTs)wasinvestigatedbydirect-currentplasmaenhancedchemicalvapordeposition(DC-PECVD).NH3gasetchesNicatalystlayertoformnanoscaleislandswhileNH3plasmaetchesthedepositedamorphouscarbon.BasedontheetchingeffectofNH3gasonNicatalyst,thedifferencesofgrowingbundlesofCNTsandsinglestrandCNTswerediscussed;specifically,theamountofoptimalNH3gasetchingisdifferentbetweenbundlesofCNTsandsinglestrandCNTs.IncontrasttotheCNTcarpetgrowth,thesinglestrandCNTgrowthrequiresshorteretchingtime(5min)thanlargecatalyticpatterns(10min)sincenanodotsalreadyformcatalystislandsforCNTgrowth.Throughremovingtheplasmapretreatmentprocess,thedamagefrombeingexposedathightemperaturesubstrateoccurringduringtheplasmagenerationtimeisminimized.Highresolutiontransmissionelectronmicroscopy(HTEM)showsfishbonestructureofCNTsgrownbyPECVD.

  • 标签: 碳纳米管 垂直排列 纳米纤维 等离子体增强化学气相沉积 生长 氨气
  • 简介:Acompactammoniagassensorwithtwogaschambersisproposedinthispaper,whosecoresensingdeviceisaU-bendingmicroringresonator.Thewaveguidesofringpartandfeedbackpartinthisresonatoraremadeofsilicononinsulator(SOI)ridgewaveguidecoveredwithZnOnanocrystalswhicharesensitivetoammoniagas.Thesensorcanmeasuretwogroupsofgassamplessimultaneously.Bycomputersimulation,weobtaintheclearsensitivitycurvesoftwogaschambersinammoniasensorwhenthegasconcentrationincreasesfrom0to4‰.Thegasconcentrationsintwochamberscanbeobtainedfromoneoutputspectrum,whichsignificantlyreducesthematerialandtimeconsumption.

  • 标签: 传感器 谐振器 氨气 U型 微环 弯曲
  • 简介:Theeffectsofsamarium(Sm)oncarbon-methanationandcatalyticactivityoftheBa-Ru-K/AC(activecarbon)catalystforammoniasynthesiswereinvestigated.Theadditionofsamariumimprovedsignificantlytheactivityandstabilityofthecatalyst.Theresultsoftemperature-programmeddesorption(H2-TPD)andin-situ-TPSRFTIRindicatedthatsamariumimpededtheadsorptionofhydrogenonthecatalystsurface,thusleadingtothehighcatalyticactivityandresistancetocarbon-methanation.XRDpatternsreve...

  • 标签: SAMARIUM carbon-methanation AMMONIA SYNTHESIS RARE earths
  • 简介:Electrolysisofammoniainalkalineelectrolytesolutionwasappliedfortheproductionofhydrogen.BothPt-loadedNifoamandPt-IrloadedNifoamelectrodeswerepreparedbyelectrodepositionandservedasanodeandcathodeinammoniaelectrolyticcell,respectively.TheelectrochemicalbehaviorsofammoniainKOHsolutionwereindividuallyinvestigatedviacyclicvoltammetryonthreeelectrodes,i.e.bareNifoamelectrode,Pt-loadedNifoamelectrodeandPt-IrloadedNifoamelectrode.ThemorphologyandcompositionofthepreparedNifoamelectrodewereanalyzedbyscanningelectronmicroscopy(SEM)andX-raydiffraction(XRD).Effectsoftheconcentrationofelectrolytesolutionandtemperatureofelectrolyticcellontheelectrolysisreactionwereexaminedinordertoenhancetheefficiencyofammoniaelectrolysis.Thecompetitionofammoniaelectrolysisandwaterelectrolysisinthesamealkalinesolutionwasfirstlyproposedtoexplainthechangesofcellvoltagewiththeelectrolysisproceeding.Atvaryingcurrentdensities,differentcellvoltagescouldbeobtainedfromgalvanostaticcurves.Thelowcellvoltageof0.58V,whichislessthanthepracticalelectrolysisvoltageofwater(1.6V),canbeobtainedatacurrentdensityof2.5mA/cm2.Basedonsomeexperimentalparameters,suchastheappliedcurrent,theresultingcellvoltageandoutputofhydrogengas,thepowerconsumptionpergramofH2producedcanbeestimated.

  • 标签: AMMONIA elelctrolysis nickel ELECTRODE hydrogen produciton
  • 简介:Nitrogen(N)applicationmayleadtonichesegregationofsoilammonia-oxidizingarchaea(AOA)andbacteria(AOB),therebyreducingthecompetitiveinteractionsbetweenAOAandAOBduetohigherammoniumsubstrateavailability.However,theadaptivemechanismsofAOAandAOBunderNenrichmentremainpoorlyunderstood.Stableisotopeprobing(SIP)microcosmincubationwasemployedtorevealcommunitychangesofactiveAOAandAOBinaloesssoilfromafieldexperimentgrowingpotatoesthatreceivednoN(control,CK),lowN(LN,75kgNha-1),andhighN(HN,375kgNha-1).Theresultsshowedthatthesoilpotentialnitrificationrate(PNR)wasmeasuredbyculturingofthesoilsamplesfromthefieldexperiment.SoilPNRwassignificantlyincreasedinHNby87.5%and67.5%comparedwithCKandLN,respectively.ComparedwithCK,the13C-amoAgenesofsoilAOAandAOBinHNhad2.58×104and1.55×106copies,representing1.6-and16.2-foldincreaserespectively.ItwasindicatedthatAOBdominatedsoilammoniaoxidation.Aphylogeneticanalysisofthe13C-amoAgeneshowedthatNapplicationsignificantlyincreasedtheproportionof54d9-likeAOAupto90%inHN,whiletheNitrososphaeragargensis-likeandNitrososphaeraviennensis-likeAOAwereinhibitedandcompletelydisappeared.NitrogenapplicationalsoresultedinthecommunityshiftofactiveAOB-dominantgroupfromNitrosospirabriensis-liketoNitrosospirasp.TCH711-like.OurstudyprovidescompellingevidencefortheemergenceandmaintenanceofactivenitrifyingcommunitiesundertheintensifiedNinputtoanagriculturalecosystem.

  • 标签: AMMONIA MONOOXYGENASE ammonia-oxidizing ARCHAEA ammonia-oxidizing bacteria
  • 简介:我们进行了在沙的土壤和黏土变得在土壤侧面在表面水,通过来自稻地的挥发的氨的损失,大米生产,氮使用效率,和氮内容里在NH4+-N的集中上决定氮申请层次的效果的大米的地试用。表面水和通过挥发失去的氨的数量里的NH4+-N的集中与增加氮申请水平增加了,并且在氮申请以后在1-3d达到顶点。更少的氨比从沙的土壤从黏土经由挥发被失去。在氮申请不同取决于舞台以后,当它被使用时,氨的数量经由挥发输了,从最高的损失到最低:支持tillering的N申请>支持圆锥花序开始的第一N顶肥(在最后4叶阶段适用)>基础化肥>支持圆锥花序开始的第二N顶肥(在最后2叶阶段适用)。经由从黏土的挥发的氨的全部的损失是10.49-87.06kg/hm2,到氮的10.92%-21.76%的等价物适用。经由从沙的土壤的挥发的氨的全部的损失是11.32-102.43kg/hm2,到氮的11.32%-25.61%的等价物适用。在表面水里经由挥发和NH4+-N的集中失去的氨的数量在氮申请以后同时达到顶点;在tillering的两个都显示出的最大值与在他们之间的比率上演从23.76%~33.65%。随氮申请水平的增加,在植物的米饭生产和氮累积增加了,但是氮使用效率减少了。在植物的瑞斯生产和氮累积比在沙的土壤在黏土是稍微更高的。在土壤,氮内容在40-50厘米的深度是最低的。在任何特定的土壤层,土壤氮内容与增加氮申请增加了水平,和土壤氮内容比在沙的土壤在黏土是更高的。以氨挥发,当氮申请水平在种季节的米饭超过了250kg/hm2时,经由挥发失去的氨的数量显著地增加了。为米饭生产,然而,合适的氮申请水平是约300kg/hm2。因此,为高庄稼收益和环境保护考虑需要,适当的氮申请水平是处于这些条件的250-300kg/hm2。

  • 标签: 氨挥发损失 氮素利用率 施氮水平 水稻产量 生长季节 NH4-N
  • 简介:TheSmBaCuMO5+δ(M=Fe,Co,Ni)(SBCM)powdersweresynthesizedbythecitratesol-gelmethodandthepowdersweresinteredtoceramicpellets.ThepowdersandsinteredceramicpelletswerecharacterizedwithXRD,TEMandSEMmeasurements.ThecathodecatalyticperformancesofSBCMceramicpelletsforammoniasynthesiswerestudiedfromwethydrogenanddrynitrogenatatmosphericpressureandlowtemperature,usingSBCMceramicpelletsascathode,Nafionprotonexchangemembraneaselectrolyte,Ni-Ce0.8Sm0....

  • 标签: Ni-SDC SmBaCuMO5+δ (M=Fe Co Ni) (SBCM)
  • 简介:WiththerisingofIGCCandthesecondgenerationPFBC-CC,andwiththedevelopmentoftech-nologyofstagedcombustiontoloweremissionofNOx,thedesulfurizationefficiencyunderreducingatmosphereisraised.Inthispaper,withtheapplicationofthefly-ashrecycleandtwo-stagecombustiontechnologiesinafluidizedbedcombustor,thedesulfurizationtestunderreducingatmosphereisdescribed.Meanwhile,ammoniainjectiontestwasalsoconducted.Resultsshowthatdesulfurizationunderreducingatmospherehashigherefficiency,andamooniainjectiondenitrificationeffectisveryperfect.

  • 标签: 硫化床 燃烧室 飞灰回收
  • 简介:MicrometeorologicalandmicroplotexperimentswereconductedinthefieldoffreshlyharvestedgreencaneinQueensland,Australia.ResultsshowedthathighammonialossoffertilizerNcouldoccurunderrelativelydryconditionswhenureaorcommercialproductofmixtureofureaandmuriateofpotashwereappliedtothesurfaceofsugarcanetrash.ThemoisturecontentinthetrashandthepHoffertilizerweretwoimportantfactorscontrollingtheprocessesofureahydrolysisandammoniavolatilization.MostoftheNinthesoilwastransformedtothenitratel-nitritefromafter70daysoffertilizerapplication.Nosignificantleachingwasfound.Urea-freeNfertilizershadhigherNrecoveriescomparedtourea-containingfertilizers.

  • 标签: 甘蔗 氮肥 氮损失 氨挥发 微气象学实验