学科分类
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18 个结果
  • 简介:Thesolubilityofferroalloyedneodymiuminmoltensaltcontainingneodymiumtrichlorideandthede-pendenceofsolubilityontemperatureandcompositionofthemeltaredeterminedbymeansofelectrochemicalmethod.Thedataobtainedareingoodagreementwithresultofchemicalanalysisofthequenchedmoltensaltsamples.

  • 标签: NEODYMIUM SOLUBILITY MOLTEN considerably stainless DISSOLUTION
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  • 简介:ThisworkpresentsabriefintroductiononthreekindsofnewlydevelopedNd3+-dopedlaserglassesinShanghaiInstituteofOpticsandFineMechanics(SIOM),China.TwoNd3+-dopedphosphateglasseswithlowerthermalexpansioncoefficientandthermalshockresistance4timeshigherthanthatofN31glassaredevelopedforlaserprocessing.Nd:SilicateandNd:Aluminateglasseswithpeakemissionwavelengthat1061and1065nm,effectiveemissionbandwidthof34and50nm,respectively,aredevelopedforExawatt-classlasersystemapplication.Fluorophosphateglasseswithlownonlinearrefractiveindex(n2=0.6-0.86)andlongfluorescencelifetime(430-510μs)areinvestigatedforthepurposeofdecreasingBintegralinhigh-powerlasersystem.Thepropertiesofalltheseglassesarepresentedandcomparedwiththoseofcommercialneodymiumlaserglasses.

  • 标签: ALUMINATE GLASS fluorophosphate GLASS HIGH-POWER LASER
  • 简介:Thecomplexofneodymiumchloridelowerhydratewithdiethylammoniumdiethyldithiocarbamate(D-DDC)wassynthesizedconvenientlyinabsolutealcoholanddryN2atmosphere.ThetitlecomplexwasidentifiedasEt2NH2[Nd(S2CNEt2)4]bychemicalandelementalanalysesandthebondingcharacteristicsofwhichwascharacterizedbyIR.TheenthalpiesofsolutionofneodymiumchloridehydrateandD-DDCinabsolutealcoholat298.15Kandtheenthalpieschangeofliquid-phasereactionofformationforEt2NH2[Nd(S2CNEt2)4]atdifferenttemperaturesweredeterminedbymicrocalorimetry.Onthebasisofexperimentalandcalculatedresults,threethermodynamicparameters(theactivationenthalpy,theactivationentropyandtheactivationfreeenergy),therateconstantandthreekineticparameters(theapparentactivationenergy,thepre-exponentialconstantandthereactionorder)ofliquid-phasereactionofformationwereobtained.Theenthalpychangeofthesolid-phasetitlereactionat298.15Kwascalculatedbyathermochemicalcycle.

  • 标签: 荧光材料 发光性能 稀土 热化学 配合物
  • 简介:DistributionandaccumulationofNd,anditseffectonsecretionofprogesteroneinmicewerestudiedusingradioisotopetracer(147Nd)technique.Followingsingleintraperitonealadministrationofneodymiumtracedwith147Ndatadoseof200mg*kg-1,unevendistributionoftheradioactiveNdoccurredinvarioustissuesandorgans.Muchamountof147Ndaccumulatesinthebone,andtheresidueincreaseswiththelapseoftime.Someamountofradioactivitywasalsodetectedineyes,bloodandbrain,buttheaccumulationdecreasedwiththetimeduetoexcretionandre-distributioninmice.Incomparisonwithcontrols,concentrationofprogesteroneisfoundtobesignificantlylowerintheserumofadministeredmice,indicatingasignificantlyinhibitoryeffectofNdonsecretionofprogesterone.

  • 标签: 小鼠 分泌物 积聚 分布 黄体酮
  • 简介:Rareearths(REs)areofvitalimportanceforthedevelopmentofnewmaterialsandgreenenergy.Magnesiumbicarbonateisoneofthemostrecyclableandenvironmental-friendlyprecipitantforREsrecoveryfromleachingsolutions.Nd2(CO3)3hasdifficultiesinindustrialproduction.Sointhisstudy,theprecipitationofneodymiumfromchloridesolutionbymagnesiumbicarbonateareinvestigated.Theeffectsoffeedingmethod,[HCO3-]/[Nd3+]moleratio,feedingspeedandreactiontemperatureonyieldandimpurity(magnesia)contentaresystematicallystudied.Resultsshowthattheimpurity(magnesia)contentdecreasesto0.010wt%withayieldapproachingto100%obtainedundertheconditionsof[HCO3-]/[Nd3+]=3.00byparallelflowadditionat50℃.Themajorimpurity(magnesia)inrareearthcarbonatesmainlypresentsintheformofphysicalabsorption,whichcanbeeasilyremovedbyscrubbing.Therefore,itoffersapromisinggreenprocessthatusesmagnesiumbicarbonatetoproduceneodymiumcarbonateduetoitscyclingofcarbondioxide,magnesiumsaltandwastewater.

  • 标签: RARE earth MAGNESIUM BICARBONATE PRECIPITATION process
  • 简介:用硝酸盐先锋,为做钕的钇铝石榴石(钇铝柘榴石)的准备的一个新奇弄干水花的帮助柠檬酸盐胶化过程阶段被开发。单相的多晶的钇铝柘榴石的合成在象800一样低的温度被完成

  • 标签: 喷雾干燥 熔化萃取 纤维 石榴石
  • 简介:Thecoordinationpolymer,(Nd(H2O)5)2(2,6-AQDS)3·2H2Owhere2,6-AQDS=2,6-anthraquinonedisulfonate,hasbeensynthesisedviaahydrothermalroute.Structurally,itconsistsoflayersofmonomericNdpolyhedrawhicharelinkedby2,6-AQDSanionsformingapolymeric,three-dimensionalnetwork.EachNdatomisninecoordinate,bondingtofivewatermoleculesandtofouroxygenatomsfromfour2,6-AQDSanionswhichinturnpillarthelayersbybridgingtwoNdatomsinonelayer,andcoordinatingtoasingleNdintheother.

  • 标签: 配位聚合物 水热法合成 晶体结构 络阴离子 氧原子
  • 简介:Nd:钇铝柘榴石先锋粉末被同类的降水,和Nd综合:钇铝柘榴石透明陶艺被真空sintering为5h在1700°C作好准备。陶器的材料被轻发射度和地排放枪环境扫描显微镜描绘。用统计和立方米科学理论,学习在在轻发射度和立体声之间的量的关系上被执行在三维的欧几里德几何学的空格的逻辑参数。这被发现Nd的发射度:有在厚度的1公里的钇铝柘榴石分别地在可见、在红外线附近的波长是大约45%和58%。发射度线性地与增加相等的范围直径增加并且当相等的范围直径是20μm时,到达单个水晶的理论价值。有每统一谷物和分离谷物的体积增加吝啬的特定的区域的发射度减少,和有增加的发射度减少在Nd意味着谷物的免费距离:钇铝柘榴石陶艺。

  • 标签: 钕掺杂钇铝石榴子石 透明陶瓷 立体学 显微结构 稀土元素
  • 简介:AIM:Tocomparesurgicalpeelingandaspirationandneodymiumyttriumgarnetlasercapsulotomyforpearlformofposteriorcapsuleopacification(PCO).METHODS:Aprospective,randomized,doubleblind,studywasdoneatRotaryEyeHospital,Maranda,Palampur,India,SantoshMedicalCollegeHospital,Ghaziabad,IndiaandLaserEyeClinic,NoidaIndia.ConsecutivepatientswithpearlformofPCOfollowingsurgery,phacoemulsification,manualsmallincisioncataractsurgeryandconventionalextracapsularcataractextraction(ECCE)foragerelatedcataract,wererandomizedtohavepeelingandaspirationorneodymiumyttriumgarnetlasercapsulotomy.Correcteddistancevisualacuity(CDVA),intra-operativeandpostoperativecomplicationswerecompared.RESULTS:Atotalof634patientsparticipatedinthestudy,and314(49.5%)patientswererandomizedtosurgicalpeelingandaspirationgroupand320(50.5%)totheNd:YAGlasergroup.Themeanpre-procedurallogMARCDVAinpeelingandneodymium:yttrium-aluminium-garnet(Nd:YAG)lasergroupwas0.80±0.25and0.86±0.22,respectively.ThemeanfinalCDVAinpeelinggroup(0.22±0.23)wascomparabletoNd:YAGgroup(0.24±0.28;t-test,P=0.240).Therewasasignificantimprovementinvisionafterboththeprocedures(P<0.001).AslightlyhigherpercentageofpatientsinNd:YAGlasergroup(283/88.3%)thaninpeelinggroup(262/83.4%)hadaCDVAof0.5(20/63)orbetterat9mo(P<0.001).Onthecontrary,patientshavingCDVAworsethan1.00(20/200)wasalsosignificantlyhigherinNd:YAGlasergroupascomparedtopeelinggroup(25/7.7%vs15/4.7%,respectively).OnapplicationofANCOVA,therewaslessthan0.001%riskthatPCOthicknessandtotallaserenergyhadnoeffectonrateofcomplicationsinNd:YAGlasergroupandlessthan0.001%riskthatPCOthicknesshadnoeffectoncomplicationsinpeelinggrouprespectively.SumofsquareanalysissuggeststhatintheNd:YAGlasergroup,thickPCOhadastrongerimpactoncomplications(Fischertestprobability,Pr<0.0001)

  • 标签: posterior capsule NEODYMIUM Elschnig pearls yttrium-aluminium-garnet
  • 简介:Theprocessingmethodappliedtothesidesurfaceisdifferentfromthemethodappliedtothelightpasssurfaceinneodymiumphosphateglass(Nd:glass),andthussubsurfacedefectsremainafterprocessing.ThesubsurfacedefectsinthesidesurfaceinfluencethegainuniformityofNd:glass,whichisakeyfactortoevaluatetheperformanceofamplifiers.Thescatteringcharacteristicsofsidesubsurfacedefectsweresimulatedbyfinitedifferencetimedomain(FDTD)Solutionssoftware.Thescatteringpowersoftheglassfabricatedbyacomputernumericalcontrol(CNC)machinewithoutcladdingweretestedatdifferentincidentangles.Thetrendofthecurvewassimilartothesimulatedresult,whilethesmallestpointwasdifferentwiththecomplextruemorphology.Thesimulationshowedthattheequivalentresidualreflectivityofthecladdingglasscanbemorethan0.1%whenthenumberofdefectsinasinglegriddingisgreaterthan50.

  • 标签: CLADDING FDTD GAIN UNIFORMITY SUBSURFACE defect
  • 简介:LargeapertureNd:phosphatelaserglassisakeyopticalelementforaninertialconfinementfusion(ICF)facility.N31,onetypeofneodymiumdopedphosphateglasses,wasdevelopedforhighpeakpowerlaserfacilityapplicationsinChina.ThecompositionandmainpropertiesofN31glassaregiven,togetherwiththoseofLHG-8,LG-770,andKGSS-0180Nd:phosphatelaserglasses,fromHoyaandSchott,andfromRussia.Thetechnologiesofpotmelting,continuousmelting,andedgecladdingoflargesizeN31phosphatelaserglassarebrieflydescribed.ThesmallsignalgainprofilesofN31glassslabsfrombothpotmeltingandcontinuousmeltingatvariousvaluesofthepumpingenergyofthexenonlamparepresented.N31glassischaracterizedbyastimulatedemissioncrosssectionof3.8×10-20cm2at1053nm,anabsorptioncoefficientof0.10–0.15%cm-1atlaserwavelength,smallresidualstressaroundtheinterfacebetweenthecladdingglassandthelaserglass,opticalhomogeneityof~2×10-6ina400mmaperture,andlaserdamagethresholdlargerthan42J/cm2fora3nspulsewidthat1064nmwavelength.

  • 标签: NEODYMIUM PHOSPHATE laser GLASS large APERTURE
  • 简介:Weproduceamaximum1.45Wlaseroutputat1064nmusinganeodymium-dopedsilicateglassfiberthathasarectangularcorewithdimensionsof~6.3μm×31.5μm.Themeasureddivergenceanglesoftheoutputlaserintwodimensionsare3.22°and1.76°,respectively.Theoutputpowerisstableandlimitedonlybytheavailablepumppower.

  • 标签: 硅酸盐玻璃 激光输出 光纤激光器 掺钕 矩形 瓦级
  • 简介:在这糊REE集中和Sr和从Furong矿石的Bailashui锡矿床的荧石的Nd同位素组成回答的在场的作者,南部的湖南省。结果证明在荧石的REE的全部的数量通常是低的,从有在学习区域的Qitianling花岗石的类似于那些的使球粒状陨石正常化的REE分发模式的0.705~8.785μg/g,与显著否定Eu异例由LREE丰富模式描绘了。荧石在范围以内在Sr同位素组成变化0.70830.7091,价值比在这个区域的主人碳酸盐岩石的那些是比花岗石并且高的那些低的。ɛ荧石的Nd(t)价值在−9.4和+10.3之间变化,两个都揭示那外壳--并且披风来源材料涉及形成矿石的热水的液体。在这张矿床上与以前的研究结合了,Bailashui锡矿床是速度集合并且仔细空间地在这个区域与花岗石的岩浆酌联系。热水的荧石是在热水的液体和海洋的碳酸盐摇的花岗石的magmatic之间的液体/岩石相互作用的产品。而在形成矿石的液体的Sr主要来自热水的液体和海洋的碳酸盐摇的花岗石的magmatic,在形成矿石的液体的REE和F从花岗石被导出,尽管在Sr同位素组成的变化不能被这二结束成员的简单混合物解释。证据证明形成矿石的液体具有外壳披风的混合起源,但是液体可能是,这不完全地一致,这可以被不同来源的液体的不同类的混合引起。

  • 标签: 萤石 同位素 锡沉淀 稀有地球元素