简介：OnthebaseofMgO-CaOcoatingmaterialTD-CA12fortundish,anewTD-CA32withhighCaOcontentwasdeveloped,ItsCaOcontentis30%-36%andMgOcontentis45%-55%,TheapplicationresultinBaosteelshowsthatTD-CA32notonlyhasthesamepropertiesasTD-CA12butalaohastheimprovedpropertiesofdisintegrationandsteelpurifing.

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简介：Thedevelopmentstatus,productiontechnologyandcharacteristicsofMgO-CaOrefractoriesareintroduced,coveringMgO-CaOclinkers,firedMgO-CaObricksandunburnedMgO-CaO-Cbricks.TheapplicationsofMgO-CaOrefractoriesinsecondaryrefiningfurnacesincludingAOD,VOD,LF-VDandGORareintroduced.

简介：DuringthereactionbetweencalciumsorbentsandSO2,calciumsorbentsarefirstcalcinedandconvertedintoCaO.CaOcanbeobtainedbycalciningCa(OH)2orCaCO3.Theporosityofthesorbentisincreasedbecauseofcalcinationandisdecreasedbecauseofsulfurization.InthecalcinationprocessH2OorCO2isescapedfromtheparticlesandporesareformedinparticles.ThereactionorconvertrateofCaOisinfluencedstronglybytheporestructurecharacters.FromCa(OH)2toCaOtheescapevelocityofH2Ooritsmasstransferisoneofthekeyfactorsinfluencingtheporeforming.Duringcalcinationprocessdifferentheatingvelocity,differentheatingtimeandtemperatureweresuggested.Thetemperaturerisingrateandcalciningtemperatureplayimportantroletotheporestructure.TheconvertratesofCaOobtainedthroughdifferentcalciningconditionswereinvestigatedexperimentally.SomeinterestingresultswereshowedthatthecalciumutilizationofCaOparticlesisdeterminednotonlybythespecialsurfaceareaandtotalporevolume,butalsobypore-sizedistribution.Themainfactorinfluencingthesulfationistheporediameterdistributionatlowersulfationtemperature.Forhigherreactiontemperaturespecificvolumeistheimportantreason.Butpore-sizedistributionisstronglyinfluencedbyheatfluxandtemperatureinthecalciningprocess.

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简介：InBaotourareearthtailingsore,thegradeofrareearthisclosetothatoftheraworenearly.Therareearthsarediscardedintailingsdamcausedbyaseriouswasteofresources.Firstofall,thedecompositionproductsofbastnaesite-andmonazite-mixedrareearthtailingsinCaOinreducingatmospherewerestudiedbymeansofX-raydiffraction(XRD).TheresultsshowthatthenormalproductsareCeO_2,Ce_2O_3,Ca_5F(PO_4)_3,andCe_(0.75)Nd_(0.25)O_(1.875),andtherearenoREPO_4andREFCO_3.Secondly,theroastedproductwasextractedinHCl,andtherelationshipamongroastingtime,roastingtemperature,CaOaddition,andextractiontemperaturewasstudiedbythequadraticregression-orthogonalanalysis.Throughanalysis,theoptimumprocessconditionsofmixedrareearthtailingsextractedareobtainedasfollows:roastingtimeof60min,roastingtemperatureof800℃,CaOadditionof30%,extractiontemperatureof80℃,andextractionratioof99.18%.

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简介：尝试用六次甲基四胺和铜试剂联合分离法分离出锰等干扰离子,解决了传统分析法对部分高锰试样中的钙镁分析不准确的问题。

简介：本文探讨Mg—CaO复合脱硫的基本原理与特点，分析了镜脱硫的特点，集合生产实际情况。从初始硫含量、粉剂消耗、喷吹速度等方面分析了Mg-CaO复合脱硫工艺效果。

简介：BycarbothermalreductionofMgOwithblackcarbonasreductionagentatahightemperature,MgOwasdepositedonthesurfaceofMgO-CaOclinker(ascoating)toimprovetheclinker'shydrationresistance.Inthepaper,effectofdepositiontemperatureandholdingtimeonthehydrationresistanceofthetreatedMgO-CaO,thedepositionmechanismandMgOcoatingkineticswereinvestigatedwithhydrationresistancetest,X-raydiffractometry(XRD)andscanningelectronicmicroscope(SEM).ResultsshowedMgOcoatinggrewina2DmodeonthesurfaceofMgO-CaOparticles;theMgOcoatingimprovedthehydrationresistanceofthecoatedMgO-CaOclinker,andthecoatedclinkerwouldbecomestrongerwhencoatedathigherdepositiontemperatureandlongerholdingtime.ThemeasurementsalsofoundthatMgOdepositionprocessvariedwiththedepositiontemperature:itwasmainlyachemical-controlledprocessattemperaturesbetween1400-1500℃,withanapparentactivationenergy(AAE)of97.8kJ·mol~(-1);itwouldchangeintoadiffusion-controlledprocesswhenthetemperaturerisingto1500-1600℃,withapparentactivationenergyof19.2kJ·mol~(-1).

简介：Coprecipitationsupercriticalfluiddryingtechnologyhasbeenemployedtosynthesizecalcia-stabilizedzirconiaultrafinepowderwithlow-costinorganicsaltsasthestartingmaterials.Thesinteringbehaviorsofthesepowderswerealsoinvestigated.Theresultsshowedthatsupercriticalfluiddryingcouldeffectivelyalleviatethehardagglomerationofgrainsduringthegeldryingprocess,andthemorphologyofthepowderretainedthenetworktextureoftheoriginalgel.Theresultingparticleswerecharacterizedbysmallparticlesize(5～20nm),bettermonodispersityandhighsurfacearea,whichgaverisetohighactivityandsinterability.Consequently,thesepowderscouldreadilybecompactedintothedesiredshapeandtheirdensificationcouldbecarriedoutinshortertimeandatlowertemperatures.Forinstance,nanometer-sizedpowdercalcinedat600℃for2hcouldbecold-pressedintoagreenbodyandsinteredat1100°for0.5htoattainadensebodywithbulkdensityof5.9718g/cm3andspecificporevolumeof0.0008cm3/g.

简介：Inthis,phasecompsitionandthermalexpansionbehaviourofCaOStabilisedrefractorieswerestudied,Specialattentionwaspaidtotheexpasionbehaviourofthreematerialswithdifferentphasecomposition,TheresearchresultsindicatedthattheexpansionbehaviourcouldbeimprovedbymodifyingthestabilizationofZrO2,whichthusleadstotheincreaseinthethermalshockresistanceandpossiblyeroionresistaceofas-obtainedCaOstabilisedZrOmaterial.

简介：High-speedrail,asanimportantachievementofintegratedinnovationofscienceandtechnology,hasafarreachingeffectonthedevelopmentoftherailwayintheworld.High-speed,convenience,comfortandenvironment-friendliness

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简介：摘要：随着人们生活水平的提高，随之也带来了一系列的环保问题，其中垃圾处理成为国内外关注的焦点问题，而目前国内垃圾处理方式，以填埋为主，占用大量土地的填埋处理方式占比高达70%，随着城市及其周边用地的紧张，大力发展垃圾焚烧产业势在必行。而在垃圾焚烧中，会产生二噁英等一些有害气体，在传统的垃圾焚烧炉里，很难处理垃圾焚烧产生的二噁英等有毒气体，以致排出废气的二噁英含量严重超标，严重危害人们的身体健康。本文提出了一种在原有的CAO垃圾焚烧炉的基础上进行改进的装置，能够最大程度上减少垃圾焚烧尾气中的二噁英等有毒气体的排出，从而促进垃圾焚烧行业的发展。

简介：摘要烧结矿是在中国高炉炼铁的主要原料，能源消耗和烧结过程的质量是影响能源消费的炼铁的重要指标，在中国采用烧结技术主要是强切粒机、燃料两次分加，偏析布料技术，采用蒸汽预热，提高混合料的温度。通过烧结工艺，可以大大提高烧结矿的质量，从而减少固体燃料的消耗，降低炼铁的总能耗。本文针对炼铁烧结时生产的情况，在实验室进行大量的烧结实验，分析CaO含量对炼铁时冶炼性能的影响。结果表明炼铁时烧结CaO对炼铁影响很大。

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简介：Thecorrosionofrefractoriesresultsfromreactivetransport,namely,transportofagentsandchemicalreactionsoftheseagentswithimpregnatedmedium.Ononehand,thetransportinvolveseitherdiffusionorimpregnationdependingonthestateofthecorrosiveagentsandthemicrostructureofthehostmedia.Ontheotherhand,chemicalreactionsmaybeverynumerousandcomplex.ThisstudyfocusedonthereactiveimpregnationofAl2O3-CaOslagintoporoushighaluminarefractory.Thetransportpropertiesoftherefractorymaterialwereidentifiedbymeansofadedicatedcapillaryrisingtest.ChemicalreactionsbetweenthesolidhighaluminaskeletonandAl2O3-CaOslaginvolvesuccessivedissolution/precipitationmechanismsformingaluminatesoflime.Contrarytothethermodynamicpropertiesofthebinarysystem,thekineticsofthesesolid/liquidreactionsisnotwellknown.Corrosiontestsassociatedwiththequenchingmethod,XRDanalyseswereperformedforabetterunderstandingofthekinetics.Theresultsofthisstudyopenupacouplingapproachforpredictingthecorrosionwearofrefractory.